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Influence of Reagent Structure on the Rate and Mechanism of the Reaction of Aryloxiranes with Benzoic Acids

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Abstract

The kinetics of the reactions of aryloxiranes (XC6H4CH(O)CH2, X = H, 4-Cl, 3-NO2, 4-NO2, and 3-Br and 4-Br in part) with arylcarboxylic acids (YC6H4(3) COOH, Y = H, 3-Br, 3-NO2, 3,5-(NO2)2, and 4-OCH3 in part) in acetonitrile have been studied at 343 K. Non-additive effects of the structural factors have been estimated quantitatively by cross-correlation analysis. The mechanism of the reactions is discussed.

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Authors and Affiliations

  1. Donets'k National University, 24 Universytets'ka Vul., 83055, Donets'k, Ukraine

    I. V. Shpan'ko & I. V. Sadovaya

Authors
  1. I. V. Shpan'ko
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  2. I. V. Sadovaya
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Shpan'ko, I.V., Sadovaya, I.V. Influence of Reagent Structure on the Rate and Mechanism of the Reaction of Aryloxiranes with Benzoic Acids. Theoretical and Experimental Chemistry 38, 125–128 (2002). https://doi.org/10.1023/A:1016096302680

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  • DOI: https://doi.org/10.1023/A:1016096302680

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