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Synthesis and Crystal Structure Investigation of Trinitrotriamminerhodium(III) [Rh(NO2)3(NH3)3]

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Abstract

Synthesis of the complex [Rh(NO2)3(NH3)3] is described. The compound crystallizes as monoclinic colorless plates. Crystal data: a = 7.176(10), b = 10.407(2), c = 10.989(2) Å, β = 93.27°, V = 819.3(2) Å3, space group \({{P2_1 } \mathord{\left/ {\vphantom {{P2_1 } m}} \right. \kern-\nulldelimiterspace} m}\), Z = 4, d calc = 2.367 g/cm3. The structure is molecular and built of neutral complexes having cis-facial configuration. The unit cell of the crystal contains two independent complexes.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    S. P. Khranenko, I. A. Baidina, S. A. Gromilov & A. V. Belyaev

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  1. S. P. Khranenko
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  2. I. A. Baidina
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  3. S. A. Gromilov
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  4. A. V. Belyaev
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Khranenko, S.P., Baidina, I.A., Gromilov, S.A. et al. Synthesis and Crystal Structure Investigation of Trinitrotriamminerhodium(III) [Rh(NO2)3(NH3)3]. Journal of Structural Chemistry 43, 142–146 (2002). https://doi.org/10.1023/A:1016090320116

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