Abstract
The mixed-ligand complexes Zn(2,\(2'\)-Bipy)(i-PrOCS2)2 (I) and Zn(2,\(2'\)-Bipy)(i-BuOCS2)2 (II) were synthesized. Their structures were solved using the X-ray diffraction data (CAD-4 diffractometer, MoK α radiation, 1873 and 1948 F hkl , R = 0.0357 and 0.0338). The crystals are triclinic with unit cell dimensions a = 10.002(2), b = 11.080(2), c = 11.756(2) Å, α = 78.46(3), β = 75.49(3), γ = 63.50(3)°, V = 1122.9(4) Å3, Z = 2, space group \(P\bar 1\) (for complex I) and a = 8.760(2), b = 12.520(3), c = 13.252(3) Å, α = 63.93(3), β = 71.10(3), γ = 88.01(3)°, V = 1225.2(5) Å3, Z = 2, space group \(P\bar 1\) (for II). The structures are based on discrete monomeric molecules. The polyhedra of Zn atoms are tetragonal pyramids (ZnN2S3, c.n. 4+1, both bidentate and monodentate \({\text{ROCS}}_{\text{2}}^ - \) ligands coordinated to the Zn atom). The packing of molecules and the character of their interaction in the structures are considered.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
S. V. Larionov, R. F. Klevtsova, S. M. Zemskova, and L. A. Glinskaya, Khim. Int. Ust. Razv., 7, No. 4, 451-461 (1999).
R. F. Klevtsova, L. A. Glinskaya, S. M. Zemskova, and S. V. Larionov, Polyhedron, 18, No. 26, 3559-3565 (1999).
S. M. Zemskova, L. A. Glinskaya, R. F. Klevtsova, et al., Zh. Strukt. Khim., 36, No. 3, 528-540 (1995).
S. M. Zemskova, L. A. Glinskaya, V. B. Durasov, et al., ibid., 34, No. 5, 157-166 (1993).
T. G. Leonova, V. N. Kirichenko, L. A. Glinskaya, et al., Koordinats. Khim., 23, No. 8, 590-595 (1997).
G. M. Sheldrick, SHELX-97, Release 97-2, University of Göttingen, Germany (1998).
L. A. Glinskaya, R. F. Klevtsova, T. G. Leonova, and S. V. Larionov, Zh. Strukt. Khim., 41, No. 1, 196-201 (2000).
R. F. Klevtsova, L. A. Glinskaya, T. G. Leonova, and S. V. Larionov, ibid., 42, No. 2, 293-301 (2001).
A. G. Orpen, L. Brammer, F. H. Allen et al., J. Chem. Soc., Dalton Trans., (Suppl.), S1-S83 (1989).
F. H. Allen, S. Bellard, M. D. Brice, et al., Acta Crystallogr., B35, 2331-2339 (1979).
C. A. Hunter and J. K. M. Sanders, J. Am. Chem. Soc., 112, 5525-5534 (1990).
R. F. Klevtsova, L. A. Glinskaya, V. G. Shchukin, and S. V. Larionov, Zh. Strukt. Khim., 42, No. 3, 536-544 (2001).
S. V. Larionov, A. A. Voityuk, L. N. Mazalov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 998-1002 (1981). 132
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Klevtsova, R.F., Glinskaya, L.A., Leonova, T.G. et al. Mixed-Ligand Complexes Zn(2,2′-Bipy)(ROCS2)2 with Mono- and Bidentate Ligands \({\text{ROCS}}_{\text{2}}^ - \) (R = i-Pr, i-Bu). Journal of Structural Chemistry 43, 125–132 (2002). https://doi.org/10.1023/A:1016086219207
Issue Date:
DOI: https://doi.org/10.1023/A:1016086219207