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Effect of conformational rigidity on the glass transition and initial decomposition temperatures of polyimides

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Abstract

The dependence of the glass transition and initial decomposition temperatures of polyperyleneimide and polynaphthylimide on the conformational rigidity was studied by the Monte Carlo, Kuhn segment, and quantum chemical AM1 methods. The corresponding linear plots can be used for estimation of the glass transition and initial decomposition temperatures when experimental determination is difficult.

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Authors and Affiliations

  1. Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    I. A. Ronova, L. B. Eylshina, A. N. Vasilyuk, A. L. Rusanov & E. G. Bulycheva

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  1. I. A. Ronova
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  2. L. B. Eylshina
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  3. A. N. Vasilyuk
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  4. A. L. Rusanov
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  5. E. G. Bulycheva
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Ronova, I.A., Eylshina, L.B., Vasilyuk, A.N. et al. Effect of conformational rigidity on the glass transition and initial decomposition temperatures of polyimides. Russian Chemical Bulletin 51, 820–824 (2002). https://doi.org/10.1023/A:1016032800689

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  • DOI: https://doi.org/10.1023/A:1016032800689

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