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Tetranuclear rhenium chalcogenide cluster complexes with a cubane core. Synthesis, structures, and properties

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Abstract

The results of studies of rhenium chalcogenide cluster complexes with the [Re4Q4] cubane core, where Q = S, Se, or Te, are reviewed. Different approaches to the synthesis of these compounds are surveyed and their properties and structures are considered. Substitution reactions in the cluster core and replacements of terminal ligands are discussed. The formation of polymers consisting of the tetranuclear rhenium chalcogenide cyanide clusters as structural building blocks is considered.

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Authors and Affiliations

  1. Siberian Branch of the Russian Academy of Sciences, Institute of Inorganic Chemistry, 3 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    Yu. V. Mironov & V. E. Fedorov

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  1. Yu. V. Mironov
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  2. V. E. Fedorov
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Mironov, Y.V., Fedorov, V.E. Tetranuclear rhenium chalcogenide cluster complexes with a cubane core. Synthesis, structures, and properties. Russian Chemical Bulletin 51, 569–580 (2002). https://doi.org/10.1023/A:1015843529164

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