Abstract
The solubilities of solid 1-hexyne in liquid argon at 87.3 and in liquid nitrogen at 77.4 K have been measured by the filtration method. The hydrocarbon contents in solutions were determined using gas chromatography. GC–MS was used to identify impurities in 1-hexyne. The experimental value of the mole fraction solubility of solid 1-hexyne in liquid argon at 87.3 K is (0.85 ± 0.19) × 10−7 and (1.25 ± 0.08) × 10−8 in liquid nitrogen at 77.4 K. The Preston–Prausnitz method was used for calculation of the solubilities of solid hydrocarbon in liquid argon in the temperature range 84.0–110.0 K and in liquid nitrogen from 64.0 to 90.0 K. The solvent–solute interaction parameters l 12 were also calculated. At 90.0 K liquid argon is a better solvent for solid 1-hexyne than is liquid nitrogen.
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References
E. Szczepaniec-Cięciak, M. Kurdziel, and L. Ulman, J. Chem. Soc. Faraday Trans. 1 85, 2695(1989).
E. Szczepaniec-Cięciak and M. Krzeczkowska, J. Solution Chem. 30, 69(2001).
M. Kurdziel, E. Szczepaniec-Cięciak, E. żarnowska, J. Stach, W. Nitek, and B. Dąbrowska, J. Solution. Chem. 30, 781(2001).
E. Szczepaniec-Cięciak and M. Krzeczkowska, J. Solution Chem. 27, 485(1998).
Cambridge Structural Database System (CSDS) 5.21/2001.
G. T. Preston and J. M. Prausnitz, Ind. Eng. Chem. Process. Design Develop. 9, 264(1970).
E. Szczepaniec-Cięciak, B. Dąbrowska, and J. M. Lagan, Cryogenics 17, 621(1977).
D. L. Lide, ed., CRC Handbook of Chemistry and Physics, 78th edn. (CRC Press, Boca Raton, FL, 1997).
J. A. Riddick, W. B. Bunger, and T. K. Sakano, Organic Solvents. Physical Properties and Methods of Purification, 4th edn., Techniques of Chemistry, Vol. II Wiley (Interscience), New York, 1986.
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Kurdziel, M., Szczepaniec-Cięciak, E., Golonka, M. et al. Solubility of Solid 1-Hexyne in Liquid Argon and Nitrogen at the Standard Boiling Points of the Solvents. Journal of Solution Chemistry 31, 253–260 (2002). https://doi.org/10.1023/A:1015825102964
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DOI: https://doi.org/10.1023/A:1015825102964