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Solubility of Solid 1-Hexyne in Liquid Argon and Nitrogen at the Standard Boiling Points of the Solvents

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Abstract

The solubilities of solid 1-hexyne in liquid argon at 87.3 and in liquid nitrogen at 77.4 K have been measured by the filtration method. The hydrocarbon contents in solutions were determined using gas chromatography. GC–MS was used to identify impurities in 1-hexyne. The experimental value of the mole fraction solubility of solid 1-hexyne in liquid argon at 87.3 K is (0.85 ± 0.19) × 10−7 and (1.25 ± 0.08) × 10−8 in liquid nitrogen at 77.4 K. The Preston–Prausnitz method was used for calculation of the solubilities of solid hydrocarbon in liquid argon in the temperature range 84.0–110.0 K and in liquid nitrogen from 64.0 to 90.0 K. The solvent–solute interaction parameters l 12 were also calculated. At 90.0 K liquid argon is a better solvent for solid 1-hexyne than is liquid nitrogen.

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Authors and Affiliations

  1. Faculty of Chemistry, Jagiellonian University, ul. R. Ingardena 3, 30-060, Kraków, Poland

    Magdalena Kurdziel, Elżbieta Szczepaniec-Cięciak, Marek Golonka, Barbara Dąbrowska & Wojciech Nitek

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  1. Magdalena Kurdziel
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  2. Elżbieta Szczepaniec-Cięciak
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  3. Marek Golonka
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  4. Barbara Dąbrowska
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  5. Wojciech Nitek
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Kurdziel, M., Szczepaniec-Cięciak, E., Golonka, M. et al. Solubility of Solid 1-Hexyne in Liquid Argon and Nitrogen at the Standard Boiling Points of the Solvents. Journal of Solution Chemistry 31, 253–260 (2002). https://doi.org/10.1023/A:1015825102964

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  • DOI: https://doi.org/10.1023/A:1015825102964

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