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Synthesis of a tris(η5-Cyclopentadienyl)(μ3-Methylidyne)trinickel cluster and its role as precursor for the tris(η5-cyclopentadienyl)(μ3-ethylidyne)trinickel cluster

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Abstract

The new tris(η5-cyclopentadienyl)(μ3-methylidyne)trinickel cluster (NiCp)3CH was obtained by slow thermal decomposition of (η2-hex-1-ene)(η5-cyclopentadienyl)-methylnickel. As well as the (methylidyne)trinickel cluster, the known (ethylidyne)trinickel cluster (NiCp)3CMe was also produced in the reaction, at a ca. 1:1 molar ratio. It appears that the (methylidyne)trinickel cluster plays a key role in the formation of the C—C bond in this reaction and is a precursor of the (ethylidyne)trinickel cluster.

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References

  1. H. Lehmkuhl, C. Krüger, S. Pasynkiewicz and J. Popławska, Organometallics, 7, 2038 (1988).

    Article  CAS  Google Scholar 

  2. H. Lehmkuhl, S. Pasynkiewicz, R. Benn and A. Rufińska, J. Organometal. Chem., 240, C27 (1982).

    Article  CAS  Google Scholar 

  3. H. Lehmkuhl, C. Naydowski and M. Bellenbaum, J. Organometal. Chem., 246, C5 (1983).

    Article  CAS  Google Scholar 

  4. H. Lehmkuhl, C. Naydowski, F. Danowski, M. Bellenbaum, R. Benn, A. Rufińska, G. Schroth, R. Mynott and S. Pasynkiewicz, Chem. Ber., 117, 3231 (1984).

    CAS  Google Scholar 

  5. H. T. Schacht and H. Vahrenkamp, J. Organometal. Chem., 381, 261 (1990).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry, Warsaw University of Technology, Koszykowa 75, 00-662, Warsaw, Poland

    Stanisław Pasynkiewicz, Włodzimierz Buchowicz & Antoni Pietrzykowski

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  1. Stanisław Pasynkiewicz
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  2. Włodzimierz Buchowicz
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  3. Antoni Pietrzykowski
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Pasynkiewicz, S., Buchowicz, W. & Pietrzykowski, A. Synthesis of a tris(η5-Cyclopentadienyl)(μ3-Methylidyne)trinickel cluster and its role as precursor for the tris(η5-cyclopentadienyl)(μ3-ethylidyne)trinickel cluster. Transition Metal Chemistry 23, 301–303 (1998). https://doi.org/10.1023/A:1015769102405

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  • DOI: https://doi.org/10.1023/A:1015769102405

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