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Reaction of Bioflavonoids with Copper(II) Acetate in Aqueous Solution

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Abstract

The reaction of dihydroquercetin, quercetin, and rutin with Cu(II) acetate in aqueous solution is studied. Quercetin and dihydroquercetin form complexes with Cu. The water-insoluble complexes are characterized as chelates of the 3,4-positions of the main γ-pyrone ring. Electronic spectroscopy showed the presence of stable polynuclear rutin complexes of composition rutin :Cu = 1:x, where x > 2.

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REFERENCES

  1. V. Cody, E. Middleton, Jr., and J. B. Harborne, Progress in Clinical and Biological Research, Vol. 213: Plant Flavonoids in Biology and Medicine: Biochemical Pharmacological and Structure-Activity Relationships, Alan R. Liss, New York (1986).

    Google Scholar 

  2. N. A. Tyukavkina, I. A. Rulenko, and Yu. A. Kolesnik, Vopr. Pitan., No. 2, 33, (1996).

  3. T. Yu. Il'yuchenok, A. I. Khomenko, L. M. Frigidova, et al., Farmakol. Toksikol., 38, 607 (1975).

    Google Scholar 

  4. S. V. Jovanovic, S. Steenken, M. Tosic, B. Marjanovic, and M. G. Simic, J. Am. Chem. Soc., 116, 4846 (1994).

    Google Scholar 

  5. E. F. Ivanenko, Biochemistry of Vitamins [in Russian], Vishcha Shkola, Kiev (1970).

    Google Scholar 

  6. C. Reddy and C. A. Hamilton, Biological Oxidation Systems, Academic Press, New York (1990).

    Google Scholar 

  7. A. B. Abkarov and Yu. A. Kharitonov, Bioinorganic Chemistry of Metals, Amino Acids, and Biocomplexants [in Russian], Tashkent (1994).

  8. P. A. Avtsin, A. A. Zhavoronkov, M. A. Rish, and L. A. Strochkova, Human Microelements [in Russian], Meditsina, Moscow (1991).

    Google Scholar 

  9. E. Balogh-Hergovich, J. Kaizer, and G. Speier, J. Mol. Catal. A: Chem., 159, 215 (2000).

    Google Scholar 

  10. I. E. Makasheva and M. T. Golovkina, Zh. Org. Khim., 43, 1640 (1973).

    Google Scholar 

  11. G. M. Saxena and T. R. Seshadry, Proc. Indian Acad. Sci., Sect. A, 46, 218 (1957).

    Google Scholar 

  12. J. E. Brown, H. Khord, R. C. Hider, and C. A. Rice-Evan, Biochem. J., 330, 1173 (1998).

    Google Scholar 

  13. J. K. Kochi and R. V. Subramian, Inorg. Chem., 4, 1527 (1965).

    Google Scholar 

  14. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, A Comprehensive Text, 2nd Ed., Interscience, New York (1966).

    Google Scholar 

  15. D. A. Davlatshoeva, Candidate Dissertation in Chemical Sciences, Kazan' (1994).

  16. I. Ya. Bershtein and Yu. L. Kaminskii, Spectrophotometric Analysis in Organic Chemistry [in Russian], Khimiya, Leningrad (1975).

    Google Scholar 

  17. A. L. Gershuns, A. A. Verozubova, and T. A. Tolstykh, Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 4, No. 1, 25 (1961).

    Google Scholar 

  18. A. P. Es′kin, V. A. Levandskii, and N. I. Polezhaeva, Khim. Rastit. Syr., No. 3, 41 (1998).

  19. Yu. Yu. Lur′e, Handbook of Analytical Chemistry [in Russian], Khimiya, Moscow (1989).

    Google Scholar 

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Mel'nikova, N.B., Ioffe, I.D. & Tsareva, L.A. Reaction of Bioflavonoids with Copper(II) Acetate in Aqueous Solution. Chemistry of Natural Compounds 38, 33–39 (2002). https://doi.org/10.1023/A:1015721529647

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  • DOI: https://doi.org/10.1023/A:1015721529647

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