Skip to main content
SpringerLink
Log in

Crystal structure and strong antiferromagnetic interaction of a terephthalate-bridged binuclear copper(II) Complex, [{Cu(dipn)}2(μ-TPHA)](ClO4)2 (dipn = N-(3-aminopropyl)-1,3-propanediamine)

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Three binuclear copper(II) complexes bridged by three different bridging ligands: μ-TPHA (terephthalato), μ-PHTA (phthalato) and μ-TCB (tetracarboxylatobenzene) have been synthesized. The crystal structure of [{Cu(dipn)}2(μ-TPHA)](ClO4)2 where dipn = N-(3-aminopropyl)-1,3-propanediamine was solved at room temperature. The [{Cudipn}2(μ-TPHA)](ClO4)2 complex consists of a μ-terephthalato bridging binuclear copper(II) cationic unit and two non-coordinated perchlorate anions. The TPHA ligand bridges in a bismonodentate fashion. The environment of the copper(II) ion is a distorted plane-square-planar coordination sphere. The magnetic properties of the three complexes have been investigated in the 75–300 K range, and show that the geometry of the CuII atom is the important factor for magnetic interactions in the terephthalato bridging binuclear copper(II) complexes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. D. Willett, D. Gattesdhi and O. Kahn, (Eds), Magneto-Structural Correlation in Exchange Coupled Systems, Reidel, Dordrecht, 1985.

    Google Scholar 

  2. M. Verdaguer, J. Gouteron, S. Jeannin, Y. Jeannin and O. Kahn, Inorg. Chem., 23, 4291 (1984).

    Article  CAS  Google Scholar 

  3. L. C. Francesconi, D. P. Corbin, A. W. Clauss, D. N. Hendrickson and G. D. Stucky, Inorg. Chem., 20, 2078 (1981).

    Article  CAS  Google Scholar 

  4. R. E. Coffman and G. R. Buetter, J. Phys. Chem., 83, 2387 (1979).

    Article  CAS  Google Scholar 

  5. F. Tinti, M. Verdaguer, O. Kahn and J. M. Savariault, Inorg. Chem., 26, 2380 (1987); M. Julve, M. Verdaguer, J. Faus, F. Tinti, J. Moratal, A. Monge and E. Guiterrez-Puebla, Inorg. Chem., 26, 3520 (1987); M. Verdaguer, J. Couteron, S. Jeannin, Y. Jeannin and O. Kahn, Inorg. Chem., 23, 4291 (1984).

    Article  CAS  Google Scholar 

  6. C. Phalguni, O. Karen, W. Karl, G. Stefan and W. Johannes, J. Am. Chem. Soc., 110, 3657 (1988).

    Article  Google Scholar 

  7. E. G. Bakalbassis, C. A. Tsipis and J. Mrozinski, Inorg. Chem., 23, 4231 (1984); 24, 4231 (1985); E. G. Bakalbassis, A. P. Bozopoulos, J. Mrozinski, P. J. Rentzeperis and C. A. Tsipis, Inorg. Chem., 27, 529 (1988); E. G. Bakalbassis, O. Kahn, P. Bergerat, S. Jeannin, Y. Jeannin and Y. Dromzee, J. Chem. Soc., Chem. Commun., 1771 (1990); E. G. Bakalbassis, C. A. Tsipis, A. P. Bozopoulos, W. Dreissig, H. Narl and J. Mrozinski, Inorg. Chim. Acta, 186, 113 (1991); E. G. Bakalbassis, P. Bergerat, O. Kahn, S. Jeannin, Y. Jeannin, Y. Dromxee and M. Guillot, Inorg. Chem., 31, 625 (1992); E. G. Bakalbassis and A. Terzis; Inorg. Chim. Acta, 218, 167 (1994).

    Google Scholar 

  8. C. E. Xanthopoulos, M. P. Siigalas, G. A. Katsoulos, C. A. Tsipis, A. Terzis, M. Mentzafos and A. Hountals, Inorg. Chem., 32, 5433 (1993).

    Article  CAS  Google Scholar 

  9. E. G. Bakalbassis, J. Mrozinski and C. A. Tsipis, Inorg. Chem., 25, 3684 (1986).

    Article  CAS  Google Scholar 

  10. Org. Synth., Coll. Vol. 5, p. 824 (1973).

  11. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, (3rd Edit.), Wiley, 1978, p. 248.

  12. H. Chen, J-Z. Zou, Z. Xu, X-Z. You, Acta Crystallogr., Sect. C, 52, 43 (1996).

    Article  Google Scholar 

  13. C. J. O'Connor, Prog. Inorg. Chem., 29, 203 (1982).

    Google Scholar 

  14. O. Kahn, Angew. Chem., 97, 837 (1985); Angew Chem., Int. Ed. Engl., 24, 834 (1985).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry & Chemical Engineering, Southeast University, Nanjing, 210096, P.R. China

    Jianzhong Zou

  2. Coordination Chemistry Institute, the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P.R. China

    Yong Wu, Chunyin Duan, Yongjiang Liu & Zheng Xu

Authors
  1. Jianzhong Zou
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yong Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chunyin Duan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yongjiang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Zheng Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zou, J., Wu, Y., Duan, C. et al. Crystal structure and strong antiferromagnetic interaction of a terephthalate-bridged binuclear copper(II) Complex, [{Cu(dipn)}2(μ-TPHA)](ClO4)2 (dipn = N-(3-aminopropyl)-1,3-propanediamine). Transition Metal Chemistry 23, 305–308 (1998). https://doi.org/10.1023/A:1015721203314

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1015721203314

Keywords

Search

Navigation