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Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)

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Abstract

Dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II) was formed in the reaction of 8-(diphenylphosphino)quinoline with nickel chloride in air. The title complex crystallized in P1 with the following cell dimensions: a = 8.5685(3) Å, b = 10.7736(2) Å, c = 13.4391(5) Å, and α = 110.447(2)°, β = 94.577(2)°; γ = 111.138(2)°, giving a volume of 1053.75(6) Å3. The trans-dichlorobis(8-(diphenylphosphinyl)quinoline) nickel(II) adapts a central symmetric distorted octahedron. The structure is compared to other nickel(II) cation complexes, and possible reasons for the bonding states are discussed.

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Authors and Affiliations

  1. State Key Laboratory of Engineering Plastics and the Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing, People's Republic of China

    Zilong Li, Wen-Hua Sun, Leyong Wang & Biao Wu

  2. State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University–Nonius B.V. Demo Lab. for X-ray Diffraction, Peking University, Beijing, People's Republic of China

    Cheng He & Chunhua Yan

Authors
  1. Zilong Li
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  2. Wen-Hua Sun
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  3. Leyong Wang
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  4. Biao Wu
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  5. Cheng He
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  6. Chunhua Yan
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Correspondence to Wen-Hua Sun.

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Li, Z., Sun, WH., Wang, L. et al. Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II). Journal of Chemical Crystallography 32, 107–111 (2002). https://doi.org/10.1023/A:1015673100877

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  • DOI: https://doi.org/10.1023/A:1015673100877

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