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Synthesis and structural characterization of the dinuclear tetrakis(guanidino) bis(2-cyanoguanidine)dicopper(II) complex

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Abstract

The synthesis and crystal structure of a new dinuclear complex Cu2(C2H4N4)2 (CH3N3)4 are reported. It crystallizes in the monoclinic system of space group P21/c, with a = 8,459(1) Å, b = 15,481(3) Å, c = 8,714(2) Å, β = 110,60(1)°, and Z = 2. The centrosymmetric molecular structure of Cu2(C2H4N4)2(CH3N3)4 comprises a tetrakis(guanidino)-bridged dinuclear copper(II) core with axially located cnge moities.

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Authors and Affiliations

  1. Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire, Tunis, Tunisie

    Mehrzia Krimi Ammar, Fatma Ben Amor, Tahar Jouini & Ahmed Driss

Authors
  1. Mehrzia Krimi Ammar
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  2. Fatma Ben Amor
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  3. Tahar Jouini
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  4. Ahmed Driss
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Correspondence to Tahar Jouini.

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Ammar, M.K., Amor, F.B., Jouini, T. et al. Synthesis and structural characterization of the dinuclear tetrakis(guanidino) bis(2-cyanoguanidine)dicopper(II) complex. Journal of Chemical Crystallography 32, 87–89 (2002). https://doi.org/10.1023/A:1015664827285

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  • DOI: https://doi.org/10.1023/A:1015664827285

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