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Synthesis and crystal structure of diaquatetra(5-methyl-1,2-oxazol-3-amine)iron(II) perchlorate

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Abstract

A new monomeric iron(II) complex of 5-methyl-1,2-oxazol-3-amine(moxa) has been synthesized and structurally characterized. Fe(II) atom is in a distorted octahedral environment with four ring N atoms of the oxazol and two water ligands. Complex molecules and uncoordinated oxazol ligands are linked together by hydrogen bonding. This complex is diamagnetic at different temperatures and no spin-crossover was observed. Magnetic susceptibility measurement was performed by Evans method in solution. IR and UV–vis spectrum of the complex was measured to investigate the solution behavior of the complex. The space group is P \(\overline 1\) (No. 2), with a = 7.4137(2), b = 10.9395(3), c = 13.5284(3) Å, α = 67.146(1), β = 88.565(1), γ = 78.556(1)°, V = 989.31(4) Å3, and Z = 1.

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References

  1. Antonio, R.J.; Carmen, M.M.; Xavier, S. Inorg.Chem. 1997, 36, 3008.

    PubMed  Google Scholar 

  2. Emanullah, M.; Renz, F.; Linert, W. Vib.Spect. 1997, 14, 1.

    Google Scholar 

  3. Gutlich, P.; Hauser, A.; Spiering, H. Angew.Chem. 1994, 33, 2024.

    Google Scholar 

  4. Zarembowitch, J.; Boillot, M.L.; Roux, C. Inorg.Chem. 1996, 35, 3975.

    PubMed  Google Scholar 

  5. Sheldrick, G.M. SHELXL86, Program for the Solution of Crystal Structures; University of G¨ottingen: Germany, 1985.

    Google Scholar 

  6. Sheldrick, G.M, SHELXL93, Program for the refinement of Crystal Structures, University of G¨ottingen: Germany, 1993.

    Google Scholar 

  7. Evans, D.F. J.Chem.Soc.1959, 2003.

  8. Hathaway, B.J.; Procter, I.M.; Slade, R.C.; Tomlinson, A.A.G. J. Chem.Soc.A 1969, 2219.

  9. Lu, Z.L.; Duan, C.Y.; Tian, Y.P.; You, X.Z.; Huang, X.Y. Inorg. Chem. 1996, 35, 2335.

    Google Scholar 

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Authors and Affiliations

  1. Art and Science Faculty, Karaelmas University, 67100, Zonguldak, Turkey

    Yakup Baran

  2. Institution of Inorganic Chemistry, Technical University of Wien, Wien, Austria

    Wolfgang Linert

Authors
  1. Yakup Baran
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  2. Wolfgang Linert
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Baran, Y., Linert, W. Synthesis and crystal structure of diaquatetra(5-methyl-1,2-oxazol-3-amine)iron(II) perchlorate. Journal of Chemical Crystallography 31, 369–372 (2001). https://doi.org/10.1023/A:1015651422973

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