Skip to main content
SpringerLink
Log in

Crystal structure of a one-dimensional ladder-shape CoII complex through hydrogen bonds with an amino-acid-like ligand 1,5-diazacyclooctane-N,N′-diacetate acid

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The crystal structure of a one-dimensional ladder-shape complex [CoL(H2O)]·2H2O, (L being 1,5-diazacyclooctane-N,N′-diacetate acid), has been determined by X-ray diffraction analysis: monoclinic, space group P21/c with a = 14.406(4) Å, b = 7.380(2) Å, c = 14.594(5) Å, β = 112.685(2)°, M r = 341.23, V = 1431.5(8) Å3, Z = 4. The CoII center is penta-coordinated by two O atoms of the carboxylic pendant arms, two nitrogen donors of the 1,5-diazacyclooctane (DACO) moiety, and a water molecule. The coordination geometry of CoII could be described as a distorted square pyramid and the DACO backbone adopts a normal boat/chair conformation. The complex forms a one-dimensional ladder-shape structure through inter- and intra-molecular O—H···O hydrogen bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Musker, W.K. Coord. Chem. Rev. 1992, 117, 133.

    Google Scholar 

  2. West, M.H.; Legg, J.I. J. Chem. Soc. 1976, 98, 6945.

    Google Scholar 

  3. Boeyens, J.C.A.; Fox, C.C.; Hancock, R.D. Inorg. Chim. Acta 1984, 87, 1.

    Google Scholar 

  4. Kanamori, K.; Broderick, W.E.; Jordan, R.F.; Willett, R.D.; Legg, J.I. J. Am. Chem. Soc. 1986, 108, 7122.

    Google Scholar 

  5. Legg, J.I.; Nielson, D.O.; Smith, D.L.; Larsen, M.L. J. Am. Chem. Soc. 1968, 90, 5030.

    Google Scholar 

  6. Nielson, D.O.; Larsen, M.L.; Willett, R.D.; Legg, J.I. J. Am. Chem. Soc. 1971, 93, 5079.

    Google Scholar 

  7. Mills, D.K.; Reibenspies, J.H.; Darensbourg, M.Y. Inorg. Chem. 1990, 29, 4364.

    Google Scholar 

  8. Farmer, P.J.; Solouki, T.; Mills, D.K.; Soma, T.; Russell, D.H.; Reibenspies, J.H.; Darensbourg, M.Y. J. Am. Chem. Soc. 1992, 114, 4601.

    Google Scholar 

  9. Buonomo, R.M.; Font, I.; Maguire, M.J.; Reibenspies, J.H.; Tuntulani, T.; Darensbourg, M.Y. J. Am. Chem. Soc. 1995, 117, 963.

    Google Scholar 

  10. Goodman, D.C.; Buonomo, R.M.; Farmer, P.J.; Reibenspies, J.H.; Darensbourg, M.Y. Inorg. Chem. 1996, 35, 4029.

    Google Scholar 

  11. Musie, G.; Reibenspies, J.H.; Darensbourg, M.Y. Inorg. Chem. 1998, 37, 302.

    Google Scholar 

  12. Lyon, E.J.; Musie, G.; Reibenspies, J.H.; Darensbourg, M.Y. Inorg. Chem. 1998, 37, 6942.

    Google Scholar 

  13. Grapperhaus, C.A.; Darensbourg, M.Y. Acc. Chem. Res. 1998, 31, 451.

    Google Scholar 

  14. Lai, C.H.; Reibenspies, J.H.; Darensbourg, M.Y. Chem. Commun. 1999, 2473.

  15. Smee, J.J.; Goodman, D.C.; Reibenspies, J.H.; Darensbourg, M.Y. Eur. J. Inorg. Chem. 1999, 539.

  16. Bu, X.H.; Du, M.; Shang, Z.L.; Zhang, R.H.; Liao, D.Z.; Shionoya, M.; Clifford, T. Inorg. Chem. 2000, 39, 4190.

    Google Scholar 

  17. Halfen, J.A.; Uhan, J.M.; Fox, D.C.; Mehn, M.P.; Que, L., Jr. Inorg. Chem. 2000, 39, 4913.

    Google Scholar 

  18. Bu, X.H.; Du, M.; Zhang, L.; Liao, D.Z.; Tang, J.K.; Zhang, R.H.; Shionoya, M. J. Chem. Soc., Dalton Trans. 2001, 593.

  19. Bu, X.H.; Du, M.; Zhang, L.; Shang, Z.L.; Zhang, R.H., Shionoya, M. J. Chem. Soc., Dalton Trans. 2001, 729.

  20. Bu, X.H.; Du, M.; Shang, Z.L.; Zhang, L.; Zhao, Q.H.; Zhang, R.H.; Shionoya, M. Eur. J. Inorg. Chem. 2001, 1551.

  21. Musker, W.K.; Steffen, E.D. Inorg. Chem. 1974, 13, 1951.

    Google Scholar 

  22. Du, M.; Shang, Z.L.; Xu, Q.; Zhang, R.H.; Leng, X.B.; Bu, X.H. Acta Crystallogr. Sect. C 2000, 56, 769.

    Google Scholar 

  23. Du, M.; Shang, Z.L.; Leng, X.B.; Bu, X.H. Polyhedron 2001, 20, 3065.

    Google Scholar 

  24. Averill, D.F.; Legg, J.I.; Smith, D.L. Inorg. Chem. 1972, 11, 2344.

    Google Scholar 

  25. Sheldrick, G.M. SHELXS-97, Program for X-ray Crystal Structure Solution; Göttingen University: Germany, 1997; Sheldrick, G.M. SHELXL-97, Program for X-ray Crystal Structure Refinement; Göttingen University: Germany, 1997.

    Google Scholar 

  26. Addison, A.W.; Rao, T.N.; Reedijk, J.; Rijn, J.V.; Verschoor, G.C. J. Chem. Soc., Dalton Trans. 1984, 1349.

  27. O'sullivan, C.; Murphy, G.; Murphy, B.; Hathaway,6B. J. Chem. Soc., Dalton Trans. 1989, 1835.

  28. Rodriguez-Fortea, A.; Alemany, P.; Alvarez, S.; Ruiz, E. Chem. Eur. J. 2001, 7, 627.

    Google Scholar 

  29. Sasada, Y. In Chemistry Handbook, 3rd ed.; The Chemical Society of Japan, Maruzen:Tokyo, 1984.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, People's Republic of China

    Miao Du, Ya-Mei Guo & Xian-He Bu

Authors
  1. Miao Du
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ya-Mei Guo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xian-He Bu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xian-He Bu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Du, M., Guo, YM. & Bu, XH. Crystal structure of a one-dimensional ladder-shape CoII complex through hydrogen bonds with an amino-acid-like ligand 1,5-diazacyclooctane-N,N′-diacetate acid. Journal of Chemical Crystallography 32, 127–131 (2002). https://doi.org/10.1023/A:1015649918624

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1015649918624

Search

Navigation