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Reaction of Fluoro-containing 3-Oxoesters with Benzaldehyde

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Abstract

Fluorinated 3-oxoesters in reactions with benzaldehyde depending on conditions afford either 2-benzylidene-3-fluoroalkyl-3-oxoesters or 3,5-dialkoxycarbonyl-2,6-dihydroxy-2,6-difluoroalkyl-4-phenyltetrahydropyrans. The latter were also obtained by treating 3-oxoesters with 2-benzylidene-3-oxoesters. Pentafluorobenzoylacetate with benzaldehyde furnishes 3,5-diethoxycarbonyl-2-pentafluorophenyl-4-phenyl-7,8,9,10-tetrafluoro-4,5-dihydrobenzo[b]oxacin-6-one.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, Ekaterinburg, 620219, Russia

    M. V. Pryadeina, O. G. Kuzueva, Ya. V. Burgart & V. I. Saloutin

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  1. M. V. Pryadeina
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  2. O. G. Kuzueva
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  3. Ya. V. Burgart
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  4. V. I. Saloutin
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Pryadeina, M.V., Kuzueva, O.G., Burgart, Y.V. et al. Reaction of Fluoro-containing 3-Oxoesters with Benzaldehyde. Russian Journal of Organic Chemistry 38, 224–231 (2002). https://doi.org/10.1023/A:1015565700648

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  • DOI: https://doi.org/10.1023/A:1015565700648

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