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Imination of Sulfur-containing Compounds: XXXV. New Preparation Method and Oxidative Benzenesulfonylimination of Unsymmetrical Disulfides

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Abstract

A new preparative method of synthesis was developed for unsymmetrical, symmetricaldisulfides consisting in sulfenylation of sodium thiolates with N-arenesulfenyl-N,N'-bis(arenesulfonyl)sulfin-amidines. Imination of unsymmetrical disulfides with sodium chloroamides of sulfonic acids occurs at the more nucleophilic sulfur atom affording N,N'-bis(arenesulfonyl)sulfinamidines and symmetrical disulfides.

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  1. Ukrainian State University of Chemical Technology, Dnepropetrovsk, 49005, Ukraine

    I. V. Koval

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Koval, I.V. Imination of Sulfur-containing Compounds: XXXV. New Preparation Method and Oxidative Benzenesulfonylimination of Unsymmetrical Disulfides. Russian Journal of Organic Chemistry 38, 232–234 (2002). https://doi.org/10.1023/A:1015517817486

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