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Adsorption of H3PW12O40 by porous carbon materials

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Abstract

Adsorption of H3PW12O40 from water and organic oxygen-containing solvents (AcOH, Me2CO, MeOH) by carbon mesoporous materials, viz., Sibunit and catalytic filamentous carbons (CFC), was studied. The amount of irreversibly sorbed heteropolyacid is 50—100 mg g–1 of support and decreases in the series of solvents: H2O > Me2CO > AcOH > MeOH. The adsorption capacity of CFC depends on the specific surface, total pore volume, and microstructure of the CFC fiber.

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References

  1. M. Misono and N. Mizuno, Bull. Chem. Soc. Jpn., 1982, 55, 400.

    Google Scholar 

  2. I. V. Kozhevnikov, Usp. Khim., 1993, 62, 510 [Russ. Chem. Rev., 1993, 62 (Engl. Transl.)].

    Google Scholar 

  3. S. M. Kulikov, M. N. Timofeeva, I. V. Kozhevnikov, V. I. Zaikovskii, L. M. Plyasova, and I. A. Ovsyannikova, Izv. Akad. Nauk SSSR, Ser. Khim., 1989, 763 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 38, 687 (Engl. Transl.)].

  4. Y. Izumi and K. Urabe, Chem. Lett., 1981, 663.

  5. G. I. Kapustin, T. R. Brueva, A. L. Klyachko, M. N. Timofeeva, S. M. Kulikov, and I. V. Kozhevnikov, Kinet. Katal., 1990, 31, 1017 [Kinet. Catal., 1990, 31 (Engl. Transl.)].

    Google Scholar 

  6. F. Lefebre, P. Dupont, and A. Auroux, React. Kinet. Catal. Lett., 55, 3.

  7. I. V. Kozhevnikov, A. Sinnema, R. J. J. Jansen, and H. van Bekkum, Chem. Lett., 1994, 27, 187.

    Google Scholar 

  8. I. A. Tarkovskaya, Okislennyi ugol´ [Oxidized Carbon], Naukova dumka, Kiev, 1981, 197 (in Russian).

  9. A. P. Karnaukhov, Adsorbtsiya. Tekstura dispersnykh i poristykh materialov [Adsorption. Texture of Dispersed and Porous Materials], Nauka, Novosibirsk, 1999, 470 (in Russian).

    Google Scholar 

  10. A. A. Fomkin, N. I. Regent, and V. I. Sinitsyn, Izv. Akad. Nauk, Ser. Khim., 2000, 1018 [Russ. Chem. Bull., Int. Ed., 2000, 49, 1012].

  11. L. B. Avdeeva, O. V. Goncharova, D. I. Kochubey, V. I. Zaikovskii, L. M. Plyasova, B. N. Novgorodov, and Sh. K. Shaikhutdinov, Appl. Catal. A, 1996, 141, 117.

    Google Scholar 

  12. Pat. RF 2146648 (2000); Chem. Abstrs., 2000, 133, 137441.

  13. P. A. Simonov, S. Yu. Troitskii, and V. A. Likholobov, Kinet. Katal., 2000, 41, 281 [Kinet. Catal., 2000, 41 (Engl. Transl.)].

    Google Scholar 

  14. A. Contescu, M. Vass, C. Contescu, K. Putyera, and J. Schwarz, Carbon, 1998, 36, 247.

    Google Scholar 

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Authors and Affiliations

  1. Siberian Branch of the Russian Academy of Sciences, G. K. Boreskov Institute of Catalysis, 5 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    M. N. Timofeeva, T. V. Reshetenko, L. B. Avdeeva, E. A. Paukshtis, A. A. Budneva, A. L. Chuvilin & V. A. Likholobov

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    M. M. Matrosova

Authors
  1. M. N. Timofeeva
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  2. M. M. Matrosova
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  3. T. V. Reshetenko
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  4. L. B. Avdeeva
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  5. E. A. Paukshtis
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  6. A. A. Budneva
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  7. A. L. Chuvilin
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  8. V. A. Likholobov
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Timofeeva, M.N., Matrosova, M.M., Reshetenko, T.V. et al. Adsorption of H3PW12O40 by porous carbon materials. Russian Chemical Bulletin 51, 243–248 (2002). https://doi.org/10.1023/A:1015491223673

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  • DOI: https://doi.org/10.1023/A:1015491223673

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