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Ring opening in epichlorohydrin and β-methylepichlorohydrin under the action of the [PtCl4]2– anion in aqueous solutions

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Russian Chemical Bulletin Aims and scope

Abstract

Oxidative addition of epoxides to [PtCl4]2– in aqueous acids affords the platinum(iv) derivatives [PtCl5(CH2CR(OH)CH2Cl)]2– (R = H (1) and Me (2)). Complex 1 was isolated as a cesium salt and characterized by IR spectroscopy. The complex is stable in acidic media; under basic conditions, the original epoxide and platinum(ii) are recovered. The formation of complex 2 was detected by 1H NMR spectroscopy.

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Authors and Affiliations

  1. National Academy of Sciences of the Ukraine, L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, 70 ul. R. Luxembourg, 83114, Donetsk, Ukraine

    I. R. Chanysheva, S. L. Litvinenko & A. N. Vdovichenko

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  1. I. R. Chanysheva
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  2. S. L. Litvinenko
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  3. A. N. Vdovichenko
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Chanysheva, I.R., Litvinenko, S.L. & Vdovichenko, A.N. Ring opening in epichlorohydrin and β-methylepichlorohydrin under the action of the [PtCl4]2– anion in aqueous solutions. Russian Chemical Bulletin 51, 354–356 (2002). https://doi.org/10.1023/A:1015480315920

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