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Electrocatalytic reactions involving the NiII—ZnII—2,2"-bipyridine system

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Abstract

Factors determining the effect of ZnII ions on the catalytic activity of the NiII complexes with 2,2"-bipyridine (bpy) in the reduction of organohalides were elucidated by cyclic voltammetry and electrolysis. The mechanism proposed involves the reduction of the NiIIbpy complex to Ni0bpy, the oxidative addition of organohalides to the Ni0bpy complex, and nickel transmetallation with the cathode-generated Zn0 to form an organozinc compound.

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References

  1. S. Torii, Synthesis, 1986, 873.

  2. S. Mabrouk, S. Pellegrini, J. C. Folest, Y. Rollin, and J. Perichon, J. Organomet. Chem., 1986, 301, 391.

    Google Scholar 

  3. G. Meyer, M. Troupel, and J. Perichon, J. Organomet. Chem., 1990, 393, 137.

    Google Scholar 

  4. M. Durandetti, S. Sibille, and J. Perichon, J. Org. Chem., 1989, 54, 2198.

    Google Scholar 

  5. A. Conan, S. Sibille, E. D´Incar, and J. Perichon, J. Chem. Soc., Chem. Commun., 1990, 48.

  6. Yu. H. Budnikova, Yu. M. Kargin, J. Perichon, and J.-Y. Nedelec, J. Organomet. Chem., 1999, 575, 63.

    Google Scholar 

  7. Yu. H. Budnikova, Yu. M. Kargin, and O. G. Sinyashin, Mendeleev Commun., 1999, 143.

  8. Yu. H. Budnikova, J. Perichon, J.-Y. Nedelec, and Yu. M. Kargin, Phosphorus Sulfur, 1999, 144-146, 881.

    Google Scholar 

  9. Yu. H. Budnikova, D. C. Yakhvarov, and Yu. M. Kargin, Mendeleev Commun., 1997, 67.

  10. Yu. H. Budnikova, Yu. M. Kargin, and O. G. Sinyashin, Phosphorus Sulfur, 1999, 144-146, 879.

    Google Scholar 

  11. M. Troupel, Y. Rollin, S. Sibille, J. F. Fauvarque, and J. Perichon, J. Organomet. Chem., 1980, 202, 435.

    Google Scholar 

  12. O. Sock, M. Troupel, and J. Perichon, Tetrahedron Lett., 1985, 26, 1509.

    Google Scholar 

  13. S. Durandetti, S. Sibille, and J. Perichon, J. Org. Chem., 1989, 54, 2198.

    Google Scholar 

  14. S. Sibille, V. Ratovelomanana, and J. Perichon, J. Chem. Soc., Chem. Commun., 1992, 283.

  15. M. Troupel, Y. Rollin, O. Sock, G. Meyer, and J. Perichon, Nov. J. Chim., 1986, 10, 593.

    Google Scholar 

  16. P. Knochel, J. J. A. Perea, and P. Jones, Tetrahedron, 1998, 8275.

  17. Yu. H. Budnikova, A. G. Kafiyatullina, Yu. M. Kargin, and O. G. Sinyashin, Zh. Obshch. Khim., 2000, 70, 1538 [Russ. J. Gen. Chem., 2000, 70 (Engl. Transl.)].

    Google Scholar 

  18. Yu. H. Budnikova, Yu. M. Kargin, and O. G. Sinyashin, Zh. Obshch. Khim., 2000, 70, 123 [Russ. J. Gen. Chem., 2000, 70 (Engl. Transl.)].

    Google Scholar 

  19. Yu. H. Budnikova, Yu. M. Kargin, and O. G. Sinyashin, Zh. Obshch. Khim., 2000, 70, 562 [Russ. J. Gen. Chem., 2000, 70 (Engl. Transl.)].

    Google Scholar 

  20. S. Sibille, V. Ratovelomanana, J. Y. Nedelec, and J. Perichon, Synlett, 1993, 425.

  21. Yu. H. Budnikova, Yu. M. Kargin, and O. G. Sinyashin, Mendeleev Commun., 1999, 193.

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Authors and Affiliations

  1. Kazan Scientific Center of the Russian Academy of Sciences, A. E. Arbuzov Institute of Organic and Physical Chemistry, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    Yu. H. Budnikova & D. G. Yakhvarov

  2. Kazan State University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    D. I. Tazeev

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  1. Yu. H. Budnikova
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  2. D. I. Tazeev
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  3. D. G. Yakhvarov
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Budnikova, Y.H., Tazeev, D.I. & Yakhvarov, D.G. Electrocatalytic reactions involving the NiII—ZnII—2,2"-bipyridine system. Russian Chemical Bulletin 51, 269–274 (2002). https://doi.org/10.1023/A:1015451509560

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