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Cyclohexane transformations over metal oxide catalysts. 1. Effect of the nature of metal and support on the catalytic activity in cyclohexane ring opening

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Abstract

The activities of monometallic Pt-, Ru-, and Rh-containing catalysts supported on Al2O3, Al2O3—F, SiO2, WO3/ZrO2, and La2Î3/ZrO2, in cyclohexane ring opening to form n-hexane were studied. The most active catalyst is Rh/Al2O3. Cyclohexane hydrogenolysis to n-hexane also occurs over the Pt/Al;>2O3 and Pt/La2Î3/ZrO2 catalysts. Ring opening over the Ru catalysts proceeds at significantly lower temperatures (210—230 °C) than over the Pt and Rh catalysts (350—400 °C), but the ruthenium systems are less selective for n-hexane formation than Rh/Al2O3 catalysts. The effects of acid-basic properties of the support and the reaction conditions on the activities of the catalytic systems in cyclohexane ring opening was studied.

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Authors and Affiliations

  1. Russian Academy of Sciences, N. D. Zelinsky Institute of Organic Chemistry, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    O. V. Masloboishchikova, T. V. Vasina, E. G. Khelkovskaya-Sergeeva & L. M. Kustov

  2. Haldor Topsoe À/S, DK-2800, Lyngby, Denmark

    P. Zeuthen

Authors
  1. O. V. Masloboishchikova
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  2. T. V. Vasina
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  3. E. G. Khelkovskaya-Sergeeva
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  4. L. M. Kustov
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  5. P. Zeuthen
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Masloboishchikova, O.V., Vasina, T.V., Khelkovskaya-Sergeeva, E.G. et al. Cyclohexane transformations over metal oxide catalysts. 1. Effect of the nature of metal and support on the catalytic activity in cyclohexane ring opening. Russian Chemical Bulletin 51, 249–254 (2002). https://doi.org/10.1023/A:1015443307743

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