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The Effect of Flame Retardant Smoke Suppressants on the Char Morphology of Plasticized PVC

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Abstract

Char formation that preserves the structural integrity of the polymer is one of the most efficient methods of reducing its flammability. Enhanced char formation from polymers such as PVC may also be associated with a decrease in smoke production, as is observed when the polymer is modified by a flame retardant smoke suppressant (FRSS) complex. A correlation had been made between the FRSS characteristics and char morphology. The effect of different flame retardant smoke suppressants on char formation has been highlighted.

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References

  1. Hirschler, M. M., ‘Soot from Fires: I. Properties and Methods of Investigation,’ Journal of Fire Science, 3 (1985), pp. 343–374.

    Google Scholar 

  2. Cullis, C. F. and Hirschler, M. M., The Combustion of Organic Polymers, The Oxford University Press, Oxford, (1981)

    Google Scholar 

  3. Lawson, D. F., Flame Retardant Polymeric Materials, eds. Lewin, M., Atlas, S. M. and Pearce, E. M. (eds), New York: Plenum Press, 1982. pp. pp 39–95.

    Google Scholar 

  4. Clements, W. R., Huang, J. M. G., and Capwell, R. J., ‘High Performance Flame Retardant/ Smoke Suppressant Additives: Char, Smoke and Off-Gas Studies,’ Japan Conference on Polymers and Plastics, Tokyo, 101–105, (July 1980)

  5. Sharma, Sunil K., Patwardhan, A. K., and Srivastava, S. K., ‘Correlation Between FRSS Characteristics of Plasticized PVCs and Their Char Morphology,’ ASIAFLAM 95, Interscience Communications Limited, London, 1995, pp. 555–560.

    Google Scholar 

  6. Sevecek, P., and Dvorak, P., ‘The Composition and Structure of Solid Char Residue after Thermal Degradation of Polystyrene, PVC and Polyamide,’ Fire and Materials, 9 (1985), pp. 145–149.

    Google Scholar 

  7. Hornsby, P. R. and Watson, C. L., ‘Magnesium Hydroxide: A Combined Flame Retardant and Smoke Suppressant Filler for Thermoplastics,’ Plastics and Rubber Processing and Applications, 6, (1986), pp. 169–175.

    Google Scholar 

  8. Michel, A., Bert, M., Guyot, A. and Lahaya, J., ‘Nature of Carbonaceous Part of Smoke in Combustion of Rigid PVC: Effect of Copper Oxide as Smoke Suppressor,’ J. Fire and Flamm, 12 (1981), pp. 72–80.

    Google Scholar 

  9. Rochow, E. G., Inorganic Synthesis, #6, McGraw Hill, 1960, pp. 147–148; Moeller, T., Inorganic Synthesis, #5, McGraw Hill, 1957, pp. 113–116, 130–131, 188–189; Fernelius, W. C., Inorganic Synthesis, #2, McGraw Hill, 1946, pp. 121–122.

    Google Scholar 

  10. Bert, M., Michel, A. and Guyot, A., ‘Reduction of Smoke Generation in Poly (vinyl chloride) Combustion,’ Fire Res., 1 (1977/78), pp. 301–311.

    Google Scholar 

  11. Sharma Sunil K., Singh, M. P., Saxena N. K., and Srivastava, S. K., ‘Assessment of Effectiveness of Smoke Suppressants: Using a He Ne Laser in a Flow System,’ Fire Mater., 17,6 (1993), pp. 271–277.

    Google Scholar 

  12. Kroenke, W. J., Metal Smoke Retarders for Poly (vinyl chloride), J. Appl. Polym Sci., 26 (1981), pp. 1167–1190.

    Google Scholar 

  13. Cullis, C. F., Gad, A. M. M., and Hirschler, M. M., ‘Metal Chelates as Flame Retardants and Smoke Suppressants for Thermoplastic Polymers,’ Eur. Polym. J., 20,7 (1984), pp. 707–711.

    Google Scholar 

  14. Sharma, Sunil K., and Sharma, T. P., ‘Morphological Features of Carbonaceous Residue: A Possible Tool to Understand FRSS Characteristics of PVC,’ unpublished paper.

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Sharma, S.K., Sharma, T.P. The Effect of Flame Retardant Smoke Suppressants on the Char Morphology of Plasticized PVC. Fire Technology 35, 276–285 (1999). https://doi.org/10.1023/A:1015440611340

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