Abstract
Computer simulations of equilibria in the Fe–C–NaCl–H2O–O2 system demonstrate that carbon has a significant influence on the composition of iron oxidation products. The effect of activated carbons with different physicochemical properties on the kinetics of heat generation during iron oxidation is studied. The process is shown to depend not only on the specific surface area and porosity of carbon but also on the stability of the complexes formed on the carbon surface via sorption of iron ions.
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Drobot, N.F., Babievskaya, I.Z., Gavrichev, K.S. et al. Role of Activated Carbon in Chemical Interactions in the Fe–C–NaCl–H2O–O2 Heat-Generating System. Inorganic Materials 38, 501–506 (2002). https://doi.org/10.1023/A:1015431307781
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DOI: https://doi.org/10.1023/A:1015431307781