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Ammonia and carbon dioxide permeability through perfluorosulfonic membranes

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Abstract

Transmembrane transport of ammonia and carbon dioxide through perfluorosulfonic membranes in ionic forms of transition metals was studied in a wide temperature interval. The different patterns of the temperature plots of the permeability coefficient of ammonia were found for different ionic forms of the membrane. An increase in the ammonia permeability with an increase in the moisture contents of the membrane also depends on its ionic form. The effects observed are explained by the different structures of water—ammonia complexes formed with metal ions. The mechanism of transmembrane transport of ammonia through perfluorosulfonic membranes in various ionic forms is discussed.

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Authors and Affiliations

  1. Federal Unitary National Enterprise “State Scientific Center of the Russian Federation: Karpov Institute of Physical Chemistry,”, 10 ul. Vorontsovo Pole, 103064, Moscow, Russian Federation

    A. V. Vorobiev

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation

    I. N. Beckman

Authors
  1. A. V. Vorobiev
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  2. I. N. Beckman
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Vorobiev, A.V., Beckman, I.N. Ammonia and carbon dioxide permeability through perfluorosulfonic membranes. Russian Chemical Bulletin 51, 275–281 (2002). https://doi.org/10.1023/A:1015403626398

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