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Structural Transformations in a Bi2O3 Crystal and in Bi2O3‐Based Solid Solutions in the Temperature Interval 25–750°C

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Abstract

The Raman scattering spectra of isostructural Bi2O3 and Bi1.8Tm0.2O3 in the course of heating have been investigated. It is shown that the sequences of structural changes with increase in temperature differ: α → δ and δ* → β → δ, respectively. In the high‐temperature region, the structure takes the form of a disordered cube irrespective of the previous history of specimens.

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REFERENCES

  1. V. G. Keramidas and W. B. White,J. Chem. Phys., 59, 1561–1562 (1973).

    Google Scholar 

  2. H. Arashi and B. Pirion, High-Temperature, High-Pressure, 11, 399–405 (1979).

    Google Scholar 

  3. V. N. Strekalovskii, Yu. M. Polezhaev, and S. F. Pal'guev, Oxides with Impurity Disordering: Composition, Structure, Phase Transformations [in Russian], Moscow (1987).

  4. H. Iwahara, T. Esaka, T. Sato, and T. Takahashi, J. Solid State Chem., 39, 173–180 (1981).

    Google Scholar 

  5. L. V. Glinskikh, V. N. Strekalovskii, G. Sh. Shekhtman, O. V. Sivtsova, É. G. Vovkotrub, and V. G. Bamburov, Materialovedenie, 3, 41–45 (2001).

    Google Scholar 

  6. N. M. Sammes, G. A. Tompsett, H. Näfe, and F. Aldinger, J. Eur. Ceram. Soc., 19, 1801–1826 (1999).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya Str., Ekaterinburg, 620219, Russia

    L. V. Ermakova & V. G. Bamburov

  2. Institute of High‐Temperature Electrochemistry, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russia

    V. N. Strekalovskii & É. G. Vovkotrub

Authors
  1. L. V. Ermakova
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  2. V. N. Strekalovskii
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  3. É. G. Vovkotrub
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  4. V. G. Bamburov
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Correspondence to L. V. Ermakova.

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Ermakova, L.V., Strekalovskii, V.N., Vovkotrub, É.G. et al. Structural Transformations in a Bi2O3 Crystal and in Bi2O3‐Based Solid Solutions in the Temperature Interval 25–750°C. Journal of Applied Spectroscopy 69, 152–154 (2002). https://doi.org/10.1023/A:1015396716886

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  • DOI: https://doi.org/10.1023/A:1015396716886

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