Skip to main content
SpringerLink
Log in

Equations for Transition from Grahame–Parsons Model to Alekseev–Popov–Kolotyrkin Model

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Equations are derived, which allow one to determine the electrode's surface coverage with adsorbate, charge, differential capacitance, and interfacial tension within the framework of a phenomenological model, for which the Grahame–Parsons and Alekseev–Popov–Kolotyrkin models are the limiting cases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Safonov, V.A., Choba, M.A., and Seropegin, Yu.D., Electrochim. Acta, 1997, vol. 42, p. 2907.

    Google Scholar 

  2. Safonov, V.A. and Choba, M.A., Elektrokhimiya, 1999, vol. 35, p. 910.

    Google Scholar 

  3. Frumkin, A.N., Z. Phys., 1926, vol. 35, p. 792.

    Google Scholar 

  4. Damaskin, B.B., Petrii, O.A., and Batrakov, V.V., Adsorbtsiya organicheskikh soedinenii na elektrodakh (Adsorption of Organic Compounds on Electrodes), Moscow: Nauka, 1968, chap. 3.

    Google Scholar 

  5. Parsons, R., J. Electroanal. Chem., 1964, vol. 7, p. 136.

    Google Scholar 

  6. Damaskin, B.B., Elektrokhimiya, 1970, vol. 6, p. 1135.

    Google Scholar 

  7. Damaskin, B., Frumkin, A., and Chizhov, A., J. Electroanal. Chem., 1970, vol. 28, p. 93.

    Google Scholar 

  8. Chizhov, A.V. and Damaskin, B.B., in Adsorbtsiya i dvoinoi elektricheskii sloi v elektrokhimii (Adsorption and Electrical Double Layer in Electrochemistry), Moscow: Nauka, 1972, p. 55.

    Google Scholar 

  9. Chizhov, A.V., Pirozhkov, S.D., and Damaskin, B.B., in Adsorbtsiya i dvoinoi elektricheskii sloi v elektrokhimii (Adsorption and Electrical Double Layer in Electrochemistry), Moscow: Nauka, 1972, p. 59.

    Google Scholar 

  10. Frumkin, A.N., Z. Phys. Chem. (Leipzig), 1925, vol. 116, p. 466.

    Google Scholar 

  11. Afanas'ev, B.N., Damaskin, B.B., Avilova, G.I., and Borisova, N.A., Elektrokhimiya, 1975, vol. 11, p. 593.

    Google Scholar 

  12. Damaskin, B.B. and Karpov, S.I., Elektrokhimiya, 1982, vol. 18, p. 3.

    Google Scholar 

  13. Damaskin, B.B., Karpov, S.I., and Dyatkina, S.L., Elektrokhimiya, 1982, vol. 18, p. 261.

    Google Scholar 

  14. Alekseev, Yu.V., Popov, Yu.A., and Kolotyrkin, Ya.M., Elektrokhimiya, 1976, vol. 12, p. 907.

    Google Scholar 

  15. Damaskin, B.B. and Baturina, O.A., Elektrokhimiya, 1999, vol. 35, p. 1348.

    Google Scholar 

  16. Grahame, D.C. and Parsons, R., J. Am. Chem. Soc., 1961, vol. 83, p. 1291.

    Google Scholar 

  17. Parry, J.M. and Parsons, R., Trans. Faraday Soc., 1963, vol. 59, p. 241.

    Google Scholar 

  18. Grahame, D.C., Chem. Rev., 1947, vol. 41, p. 441.

    Google Scholar 

  19. Perchenko, O.A. and Damaskin, B.B., Elektrokhimiya, 1986, vol. 22, p. 120.

    Google Scholar 

  20. De Levie, R., J. Electrochem. Soc., 1971, vol. 118, p. 185C.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Moscow State University, Vorob'evy gory, Moscow, 119899, Russia

    B. B. Damaskin

Authors
  1. B. B. Damaskin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Damaskin, B.B. Equations for Transition from Grahame–Parsons Model to Alekseev–Popov–Kolotyrkin Model. Russian Journal of Electrochemistry 38, 339–344 (2002). https://doi.org/10.1023/A:1015355801265

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1015355801265

Keywords

Search

Navigation