Abstract
Kinetics of processes occurring during anodic dissolution of Li x C6 electrodes formed in structures of carbonized fiber and cloth (CC) in solutions of lithium perchlorate in a mixture of propylene carbonate and dimethoxyethane is studied. It is shown that the Li x C6 (CC) electrodes have an approximately three times greater intercalation capacity, which is caused by specific features of the structure of CC. Values of the initial concentration of lithium defects in the structure of a surface layer of the CC matrix and the diffusion coefficients for lithium in the temperature range 293–323 K are calculated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Chudinov, E.F., Maier, Z.F., Timofeeva, N.V., and Kedrinskii, I.A., IV mezhd. konf. Fundamental'nye problemy elektrokhimicheskoi energetiki (Proc. IV Int. Conf on Fudamental Problems of Electrochemical Power Engineering), Saratov: Saratov. Gos. Univ., 1999, p. 139.
Joho, F., Novak, P., Haas, O., and Honnier, A., Chimia, 1997, vol. 51, p. 645.
Imhor, R. and Novak, P., Chimia, 1997, vol. 51, p. 650.
Aurbach, D., Ein–Eli, Y., and Markovsky, B., J. Electrochem. Soc., 1995, vol. 142, p. 2882.
Billaud, D., Naji, A., and Willman, P., J. Chem. Soc., Chem. Commun., 1995, no. 18, p. 1867.
Tran Tri and Kinoshita Kim, J. Electroanal. Chem., 1995, vol. 386, p. 221.
Shu, Z.X., Millan, R.S., and Murray, J.J., J. Electrochem. Soc., 1993, vol. 140, p. 922.
Morita, M., Ishimura, F., Ishikawa, M., and Matsuda, Y., J. Electrochem. Soc., 1996, vol. 143, p. 26.
Skundin, A.M. and Egorkina, O.Yu., Elektrokhimiya, 1995, vol. 31, p. 373.
Takami, N., Satoh, A., Ohzaki, T., and Kanda, M., Electrochim. Acta, 1997, vol. 42, p. 2537.
Jamanishi, N. and Jamamoto, O., Solid State Ionics, 1998, vol. 107, p. 135.
Takami, N., Satoh, A., Ohzaki, T., et al., J. Electrochem. Soc., 1998, vol. 145, p. 478.
Fialkov, A.S., Uglerod, mezhsloevye soedineniya i kompozity na ego osnove (Carbon and Carbon–based Interlayer Compounds and Composites), Moscow: Aspekt, 1997.
Handbook of Composites, Lubin, G., Ed., New York: Van Nostrand, 1982, vol. 1.
Ubbelohde, A. and Lewis, F., Graphite and Its Crystal Compounds, Oxford: Clarendon, 1960.
Trace Analysys: Physical Methods, Morrison, G.H., Ed., New York: Wiley Interscience, 1965.
Popova, S.S., Kabanov, B.N., Alekseeva, L.A., et al., Elektrokhimiya, 1985, vol. 21, p. 38.
Butler, J., Adv. Electrochem. Electrochem. Eng., 1970, vol. 7, p. 77. Translated under the title Elektrokhimiya metallov v nevodnykh rastvorakh, Moscow: Mir, 1974, p. 221.
Pominova, T.V., Popova, S.S., and Ol'shanskaya, L.N., Elektrokhimiya, 2000, vol. 36, p. 448.
Tysyachnyi, V.P. and Ksenzhek, O.S., Elektrokhimiya, 1976, vol. 12, p. 1161.
Ptitsyn, M.V., Rakhmilevich, Ya.R., and Tikhonov, K.I., Elektrokhimiya, 1980, vol. 16, p. 740.
Popova, S.S. and Ol'shanskaya, L.N., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1988, vol. 31, p. 84.
Popova, S.S., Lebedenko, E.A., Plugin, I.V., et al., Elektrokhimiya, 1989, vol. 25, p. 287.
Guerard, D. and Herold, A., Carbon, 1975, vol. 13, p. 337.
Kaminimura, N., Phys. Today, 1987, no. 1, p. 64.
Matsumura, Y., Wang, S., Nakagava, Y., and Yamaguchi, C., Synth. Met., 1997, vol. 85, p. 1411.
Rabinovich, V.A. and Khavin, Z.Ya., Kratkii khimicheskii spravochnik (Concise Handbook of Chemistry), Leningrad: Khimiya, 1978, p. 22.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ol'shanskaya, L.N., Popova, S.S., Pominova, T.V. et al. Kinetics of Anodic Dissolution of Lithium out of Li x C6 Electrodes in Nonaqueous Lithium Perchlorate Solutions. Russian Journal of Electrochemistry 38, 356–361 (2002). https://doi.org/10.1023/A:1015327619012
Issue Date:
DOI: https://doi.org/10.1023/A:1015327619012