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Capacitance of the Electrical Double Layer on Liquid Hg–Ga Alloy in Aqueous Solutions

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Abstract

Differential capacitance curves on an Hg–Ga electrode are obtained in aqueous solutions of various composition. An Hg–Ga electrode containing 2.1 at. % Hg to a high accuracy models electrochemical properties of a liquid Hg electrode at negative charges. This result can justify the approach according to which studying liquid In–Ga, Tl–Ga, Cd–Ga, and Pb–Ga alloys permit qualitative characterization of lyophilic properties of corresponding solid alloys.

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Authors and Affiliations

  1. Russian Academy of Sciences, Frumkin Institute of Electrochemistry, Leninskii pr. 31, Moscow, 117071, Russia

    V. V. Emets

  2. Moscow State University, Vorob'evy gory, Moscow, 119899, Russia

    B. B. Damaskin

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  1. V. V. Emets
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  2. B. B. Damaskin
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Emets, V.V., Damaskin, B.B. Capacitance of the Electrical Double Layer on Liquid Hg–Ga Alloy in Aqueous Solutions. Russian Journal of Electrochemistry 38, 450–453 (2002). https://doi.org/10.1023/A:1015308509443

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