Abstract
This study concerns an attempt to enhance the resistance to high-temperature isothermal and cyclic oxidation of Ti in dry air by laser-surface alloying (LSA) with Si and Si+Al. LSA was carried out by codeposition of alloy powders during lasing under the predetermined, optimum-processing routine that ensured formation of a compact, well-adherent, crack-free and homogeneous alloyed zone. The results of oxidation kinetics in the temperature range 950–1150 K for 1–400 hr indicate that surface alloying with Si imparts excellent oxidation resistance up to 1050 K. However, at a higher temperature of 1150 K, surface alloying with 3Si+Al yields a better resistance to oxidation. A detailed characterization of the microstructure and distribution of the phases within the scale and alloyed zone following oxidation studies has been undertaken to suggest the possible mechanism for enhanced oxidation resistance of Ti imparted by laser-surface alloying.
Similar content being viewed by others
REFERENCES
M. J. Donachie, Jr., Titanium and Titanium Alloys (ASM, Metals Park, OH, 1982), p. 3.
T. B. Massalski (editor-in-chief ), in Binary Alloy Phase Diagrams, Vol. 2 (ASM, Metals Park, OH, 1987), p. 2924.
R. Kossowosky and S. C. Singhal (eds.), in Surface Engineering (NATO-ASI Series, 1984).
A. Kabbaj, A. Galerie, and M. Caillet, J. Less-Common Met. 108, 1 (1985).
C. J. Rosa, Oxid. Met. 17, 359 (1982).
A. Abba, A. Galerie, and M. Caillet, Ann. Chim. 8, 191 (1983).
H. A. Lipsitt, Mater. Res. Soc. Symp. Proc. 39, 351 (1985).
J. L. Murray, in Phase Diagram of Binary Ti Alloys, J. L. Murray, ed. (ASM, Metals Park, OH, 1987), p. 289.
J. H. Abboud and D. R. F. West, Mater. Sci. Technol. 7, 353 (1991).
G. Welsch and A. I. Kahveci, in Oxidation of High Temperature Intermetallics, T. Grobstein, and J. Doychak, eds. (TMS Warrendale, PA, 1989), p. 207.
G. H. Meier, B. Appalonia, R. A. Perkins, and K. T. Chiang, in Oxidation of High Temperature Intermetallics, T. Grobstein and J. Doychak, eds. (TMS, Warrendale, PA, 1989), p. 185.
P. A. Molian, in Surface Modification Technologies-An Engineer's Guide, T. S. Sudarshan, ed. (Marcel Dekker, New York, 1989), p. 421.
C. W. Draper and J. M. Poate, Intern. Met. Rev. 30, 2 (1985).
B. L. Mordike, in Materials Science and Technology Vol. 15, R. W. Cahn, P. Haasen, and E. J. Kramer, eds (VCH, Weinheim, 1993), p. 111.
L. E. Rehn, S. T. Picraux, and H. Weidersich, in Surface Alloying by Ion, Electron and Laser Beams, L. E. Rehn, S. T. Picraux, and H. Weidersich, eds. (ASM, Metals Park, OH, 1987), p. 1.
A. Y. Fasasi, S. K. Roy, A. Galerie, M. Pons, and M. Caillet, Mater. Lett. 13, 204 (1992).
J. Dutta Majumdar, X. He, A. Weisheit, B. L. Mordike, and I. Manna, Lasers Eng. 7, 89 (1998).
J. Dutta Majumdar, A. Weisheit, B. L. Mordike, and I. Manna, Mater. Sci. Eng. A266, 123 (1999).
S. A. Kekare, D. K. Shelton, and P. B. Aswath, in Oxidation of High Temperature Intermetallics (The Minerals, Metals and Materials Society, Warrendale, PA, 1993), p. 325.
J. Dutta Majumdar, B. V. S. Asokebabu, and I. Manna, A One Dimensional Heat Transfer Model of Laser Surface Alloying, in preparation.
E. A. Brandes (ed.), in Smithells Metals Reference Book (Butterworths, London, 1968), p. 14–1.
C. Beranger and C. Coddet, J. Microscop. Spectros. Electron 5, 793 (1980).
J. E. Lopes Gomes and A. M. Huntz, Oxid. Met. 13, 249 (1980).
A. M. Chaze and C. Coddet, Oxid. Met. 27, 1 (1987).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dutta Majumdar, J., Mordike, B.L., Roy, S.K. et al. High-Temperature Oxidation Behavior of Laser-Surface-Alloyed Ti with Si and Si + Al. Oxidation of Metals 57, 473–498 (2002). https://doi.org/10.1023/A:1015300405051
Issue Date:
DOI: https://doi.org/10.1023/A:1015300405051