Skip to main content
SpringerLink
Log in

Preparation and characterization of highly dispersed V2O5/SiO2prepared by a CVD method

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Highly dispersed V2O5/SiO2(CVD catalyst) was prepared by the reaction of vaporized VO(OPri)3 with silica at 293 K, whose process was followed by an IR technique. The rate of propylene photooxidation increased with an increase in V2O5 loading for CVD catalysts, but leveled off for impregnated ones. The CVD catalysts were characterized by XAFS and photoluminescence spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. S. Yoshida et al. eds.: Characterization of Solids and Catalysis; Catalysis Society of Japan, Kodansha, Tokyo, 1985.

    Google Scholar 

  2. H. Kanai, S. Osaka: React. Kinet. Catal. Lett., 70, 105 (2000).

    Google Scholar 

  3. N. Katada, T. Toyama, M. Niwa: J. Phys. Chem., 98, 7647 (1994).

    Google Scholar 

  4. M. Niwa: Shokubai(Catalysts), 34, 221 (1992).

    Google Scholar 

  5. D.C. Bradley, R.C. Mehrotra, D.P. Gauer: Metal Alkoxides. Academic Press, New York 1978.

    Google Scholar 

  6. G.C. Bond, P. Konig: J. Catal., 77, 309 (1982).

    Google Scholar 

  7. H. Miyata, K. Fujii, T. Ono, Y. Kubokawa, Y. Ohno, F. Hatayama: J. Chem. Soc., Faraday Trans., 1, 83, 675 (1987).

    Google Scholar 

  8. K. Inumaru, T. Okuhara, M. Misono: J. Phys. Chem., 95, 4826 (1991).

    Google Scholar 

  9. M. Anpo, M. Sunamoto, M. Che: J. Phys. Chem., 93, 1187 (1989).

    Google Scholar 

  10. N.D. Scott, J.F. Walker, V.L. Hansley: J. Am. Chem. Soc., 58, 2442 (1936).

    Google Scholar 

  11. We appreciate Dr. Yamazaki of Tohoku University for giving us his in–situ IR cell specification described in Langmuir, 4, 433 (1988).

    Google Scholar 

  12. T. Tanaka, H. Yamashita, R. Tsuchitani, T. Funabiki, S. Yoshida: J. Chem. Soc., Faraday Trans., 84, 2987 (1988).

    Google Scholar 

  13. L.H. Lyttle: Infrared Spectra of Adsorbed Species, Chapter 10. Academic Press, London, (1966).

    Google Scholar 

  14. B.A. Morrow, I.A. Cody: J. Phys. Chem., 77, 1465 (1973).

    Google Scholar 

  15. B.A. Morrow, I.A. Cody, L.S.M. Lee: J. Phys. Chem., 80, 2761 (1976).

    Google Scholar 

  16. A. Bianconi: X–Ray Absorption, D.C. Koningsberger, R. Prins, eds., p. 573. Wiley Interscience, New York 1988.

    Google Scholar 

  17. S. Yoshida, T. Tanaka, T. Hanada, T. Hiraiwa, H. Kanai, T. Funabiki: Catal. Lett., 12, 277 (1992).

    Google Scholar 

  18. S. Yoshida, T. Tanaka, Y. Nishimura, H. Mizutani, T. Funabiki: Proc. 9th Intern. Cong. Catal., M.J. Phillips and T. Ternan eds., Vol. 3, 1473 (1988). The Chemical Institute of Canada, Ottawa

    Google Scholar 

  19. M. Anpo, I. Tanahashi, Y. Kubokawa: J. Phys. Chem., 84, 3440 (1980).

    Google Scholar 

  20. M. Iwamoto, H. Furukawa, K. Matsukami, T. Takenaka, S. Kagawa: J. Am. Chem. Soc., 105, 3719 (1983).

    Google Scholar 

  21. H.H. Patterson, J. Cheng, S. Despres, M. Sunamoto, M. Anpo: J. Phys. Chem., 95, 8813 (1991).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto, 606-8585, Japan

    Hiroyoshi Kanai

  2. Division of Molecular Engineering, School of Engineering, Kyoto University, Sakyo-ku, Kyoto, 606-8501, Japan

    Tatsuya Yoshikawa, Tadahide Sone & Yasuo Nishimura

Authors
  1. Hiroyoshi Kanai
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tatsuya Yoshikawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Tadahide Sone
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yasuo Nishimura
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hiroyoshi Kanai.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kanai, H., Yoshikawa, T., Sone, T. et al. Preparation and characterization of highly dispersed V2O5/SiO2prepared by a CVD method. Reaction Kinetics and Catalysis Letters 75, 213–224 (2002). https://doi.org/10.1023/A:1015282409268

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1015282409268

Search

Navigation