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Adsorption, Migration and Reactions of Hydrocarbons on Zeolites Observed by Ftir Spectroscopy

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Abstract

The adsorption, migration and reactions of hydrocarbons on zeolites studied by FTIR spectroscopy are briefly reviewed. At low temperatures, alkyl-BAS (Brønsted acid sites) and π-BAS complexes were first formed before protonation of olefins. For 1-butene, it underwent double bond migration (DBM) to form cis- and trans-2-butenes. With increasing temperature, oligomerization occurred and resulted in highly branched dimer, e.g., 3,4-dimethyl-3-hexene. Compared with 1-butene, isobutene can oligomerize at much lower temperature and formed dimerized alkoxy species, even on isolated silanols of zeolites. Upon adsorption of cyclic olefins such as 1-methylcyclopentene, alkenyl carbenium ions were formed at temperatures as low as 150 K. The adsorption of butenes on ferrierite indicates the existence of energy barriers for their intercalation into the pores. The H/D isotope exchange reaction of alkanes with acidic hydroxyl groups of zeolites will also be discussed.

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References

  1. A. Corma, Chem. Rev. 95 (1995) 559.

    Google Scholar 

  2. C. Marcilly, Stud. Surf. Sci. Catal. 135 (2001) 37.

    Google Scholar 

  3. R.A. van Santen and G.J. Kramer, Chem. Rev. 95 (1995) 637.

    Google Scholar 

  4. R.A. van Santen, Catal. Today 38 (1997) 377.

    Google Scholar 

  5. A.G. Stepanov, K.I. Zamaraev and J.M. Thomas, Catal. Lett. 13 (1992) 407.

    Google Scholar 

  6. A.G. Stepanov, Catal. Today 24 (1995) 341.

    Google Scholar 

  7. J.F. Haw, J.B. Nicholas, T. Xu, L.W. Beckand D.B. Ferguson, Acc. Chem. Res. 29 (1996) 259.

    Google Scholar 

  8. G.J. Kramer and R.A. van Santen, J. Am. Chem. Soc. 117 (1995) 1766.

    Google Scholar 

  9. P.E. Sinclair, A. de Vries, P. Sherwood, C.R.A. Catlow and R.A. van Santen, J. Chem. Soc., Faraday Trans. 94 (1998) 3401.

    Google Scholar 

  10. V.B. Kazansky, Catal. Today 51 (1999) 419.

    Google Scholar 

  11. M. Boronat, P. Viruela and A. Corma, J. Phys. Chem. B 103 (1999) 7809.

    Google Scholar 

  12. M. Boronat, P. Viruela and A. Corma, Phys. Chem. Chem. Phys. 2 (2000) 3327.

    Google Scholar 

  13. G. Spoto, S. Bordiga, G. Ricchiardi, D. Scarano, A. Zecchina and E. Borello, J. Chem. Soc., Faraday Trans. 90 (1994) 2827.

    Google Scholar 

  14. A. Zecchina, F. Geobaldo, G. Spoto, S. Bordiga, G. Ricchiardi, R. Buzzoni and G. Petrini, J. Phys. Chem. 100 (1996) 16584.

    Google Scholar 

  15. F. Geobaldo, G. Spoto, S. Bordiga, C. Lamberti and A. Zecchina, J. Chem. Soc., Faraday Trans. 93 (1997) 1243.

    Google Scholar 

  16. J.A. Lercher, C. Gründling and G. Eder-Mirch, Catal. Today 27 (1996) 353.

    Google Scholar 

  17. A.G. Stepanov, M.V. Luzgin, V.N. Romannikov, V.N. Sidelnikov and E.A. Paukshtis, J. Catal. 178 (1998) 466.

    Google Scholar 

  18. T. Armaroli, M. Trombetta, A.G. Alejandre, J.R. Solis and G. Busca, Phys. Chem. Chem. Phys. 2 (2000) 3341.

    Google Scholar 

  19. M. Trombetta, A.G. Alejandre, J.R. Solis and G. Busca, App. 198 (2000) 81.

    Google Scholar 

  20. M. Trombetta, T. Armaroli, A.G. Alejandre, H. Gonzalez, J.R. Solis and G. Busca, Catal. Today 65 (2001) 285.

    Google Scholar 

  21. J. Ryczkowski, Catal. Today 68 (2001) 263.

    Google Scholar 

  22. F. Wakabayashi, J. Kondo, A. Wada, K. Domen and C. Hirose, J. Phys. Chem. 97 (1993) 10761.

    Google Scholar 

  23. F. Wakabayashi, J.N. Kondo, K. Domen and C. Hirose, J. Phys. Chem. 99 (1995) 10573.

    Google Scholar 

  24. F. Wakabayashi, T. Fujino, J.N. Kondo, K. Domen and C. Hirose, J. Phys. Chem. 99 (1995) 14805.

    Google Scholar 

  25. F. Wakabayashi, J.N. Kondo, K. Domen and C. Hirose, J. Phys. Chem. 100 (1996) 4154.

    Google Scholar 

  26. F. Wakabayashi, J.N. Kondo, K. Domen and C. Hirose, Micropor. Mater. 8 (1997) 29.

    Google Scholar 

  27. F. Wakabayashi, J.N. Kondo, K. Domen and C. Hirose, J. Phys. Chem. 100 (1996) 1442.

    Google Scholar 

  28. F. Wakabayashi, M. Kashitani, T. Fujino, J.N. Kondo, K. Domen and C. Hirose, Stud. Surf. Sci. Catal. 105 (1997) 1739.

    Google Scholar 

  29. B. Lee, J.N. Kondo, K. Domen and F. Wakabayashi, J. Mol. Catal. 137 (1998) 129.

    Google Scholar 

  30. J.N. Kondo, F. Wakabayashi and K. Domen, J. Phys. Chem. B 102 (1998) 2259.

    Google Scholar 

  31. E. Yoda, J.N. Kondo, F. Wakabayashi and K. Domen, Appl. Catal. A 194-195 (2000) 275.

    Google Scholar 

  32. J.N. Kondo, E. Yoda, F. Wakabayashi and K. Domen, Catal. Today 63 (2000) 305.

    Google Scholar 

  33. J.N. Kondo, K. Domen and F. Wakabayashi, J. Phys. Chem. B 101 (1997) 5477.

    Google Scholar 

  34. J.N. Kondo, L. Shao, F. Wakabayashi and K. Domen, J. Phys. Chem. B 101 (1997) 9314.

    Google Scholar 

  35. J.N. Kondo, K. Domen and F. Wakabayashi, Micropor. Mesopor. Mater. 21 (1998) 429.

    Google Scholar 

  36. J.N. Kondo, L. Shao, F. Wakabayashi and K. Domen, Catal. Lett. 47 (1997) 129.

    Google Scholar 

  37. J.N. Kondo, F. Wakabayashi and K. Domen, Catal. Lett. 53 (1998) 215.

    Google Scholar 

  38. H. Ishikawa, E. Yoda, J.N. Kondo, F. Wakabayashi and K. Domen, J. Phys. Chem. B 103 (1999) 568.

    Google Scholar 

  39. J.N. Kondo, H. Ishikawa, E. Yoda, F. Wakabayashi and K. Domen, J. Phys. Chem. B 103 (1999) 8538.

    Google Scholar 

  40. J.N. Kondo, E. Yoda, H. Ishikawa, F. Wakabayashi and K. Domen, J. Catal. 191 (2000) 275.

    Google Scholar 

  41. S. Yang, J.N. Kondo and K. Domen, Stud. Surf. Sci. Catal. 135 (2001) 217.

    Google Scholar 

  42. S. Yang, J.N. Kondo and K. Domen, Chem. Comm. (2001) 2008.

  43. S. Yang, J.N. Kondo and K. Domen, J. Phys. Chem. B 105 (2001) 7878.

    Google Scholar 

  44. S. Yang, J.N. Kondo and K. Domen, Catal. Today, in press.

  45. B. Lee, J.N. Kondo, F. Wakabayashi and K. Domen, Bull. Chem. Soc. Jpn. 71 (1998) 2149.

    Google Scholar 

  46. B. Lee, J.N. Kondo, F. Wakabayashi and K. Domen, Catal. Lett. 59 (1999) 51.

    Google Scholar 

  47. F. Wakabayashi and K. Domen, Catal. Surv. Jpn. 1 (1997) 181.

    Google Scholar 

  48. T. Shimanouchi, Tables of Molecular Vibrational Frequencies, NSRDS-NBS, (1972), p. 39.

  49. A.J. Barnes and J.D.R. Howells, J. Chem. Soc., Faraday Trans. 269 (1973) 532.

    Google Scholar 

  50. C.L. O'Young, R.J. Pellet, D.G. Casey, J.R. Ugolini and R.A. Sawicki, J. Catal. 151 (1995) 467.

    Google Scholar 

  51. W.Q. Xu, Y.G. Yin, S.L. Suib, J.C. Edwards and C.L. O'Young, J. Phys. Chem. 99 (1995) 758.

    Google Scholar 

  52. W.E. Farneth and R.J. Gorte, Chem. Rev. 95 (1995) 615.

    Google Scholar 

  53. K.I. Zamaraev and J.M. Thomas, Adv. Catal. 41 (1996) 335.

    Google Scholar 

  54. I. Kirisci, H. Förster, G. Tasi and J.B. Nagy, Chem. Rev. 99 (1999) 2085.

    Google Scholar 

  55. J. F. Haw, B.R. Richadson, I.S. Oshiro, N.D. Lazo and A.J. Speed, J. Am. Chem. Soc. 111 (1989) 2052.

    Google Scholar 

  56. F.G. Oliver, F.J. Munson and J.F. Haw, J. Phys. Chem. 96 (1992) 8106.

    Google Scholar 

  57. T. Xu and J.F. Haw, J. Am. Chem. Soc. 116 (1994) 7753.

    Google Scholar 

  58. J.F. Haw, J.B. Nicholas, W. Song, F. Deng, Z. Wang, T. Xu and C.S. Heneghan, J. Am. Chem. Soc. 122 (2000) 4763.

    Google Scholar 

  59. J.R. Durig, A.C. Shing, W.E. Bucy and C.J. Wurrey, Spectrochimica Acta 34A (1978) 525.

    Google Scholar 

  60. T.B. Malloy, Jr., F. Fisher, J. Laane and R.M. Hedges, J. Mol. Spectro. 40 (1971) 239.

    Google Scholar 

  61. N.C. Deno, in: Carbonium Ions, Vol. 2, eds. G.A. Olah and P. von. R. Schleyer (Wiley-Interscience, New York, 1970) ch.18.

    Google Scholar 

  62. A.V. Demidov and A.A. Davydov, Mater. Chem. Phys. 39 (1994) 13.

    Google Scholar 

  63. C. Pazè, B. Sazak, A. Zecchina and J. Dwyer, J. Phys. Chem. B 103 (1999) 9978.

    Google Scholar 

  64. P. Buzek, P. von R. Schleyer, H. Vanèik, Z. Mihalic and J. Gauss, Angew. Chem. Int. Ed. Engl. 33 (1994) 448.

    Google Scholar 

  65. G.J. Kramer, R.A. van Santen, C.A. Enmeis and A.K. Nowak, Nature 363 (1993) 529.

    Google Scholar 

  66. V.B. Kazansky, M.V. Frash and R.A. van Santen, Catal. Lett. 28 (1994) 211.

    Google Scholar 

  67. S.R. Blaszkowski, M.A.C. Nascimento and R.A. van Santen, J. Phys. Chem. B 100 (1996) 3463.

    Google Scholar 

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Authors and Affiliations

  1. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan

    Shuwu Yang, Junko N. Kondo & Kazunari Domen

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  1. Shuwu Yang
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  2. Junko N. Kondo
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Yang, S., Kondo, J.N. & Domen, K. Adsorption, Migration and Reactions of Hydrocarbons on Zeolites Observed by Ftir Spectroscopy. Catalysis Surveys from Asia 5, 139–149 (2002). https://doi.org/10.1023/A:1015123918294

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