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Decomposition of Nitrogen Oxides on Palladium and Angle-Resolved Measurements of Desorbing Products

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Abstract

Recent angle-resolved measurements of desorbing products were reviewed for decomposition of nitrogen oxides on noble metals. Two pathways for the removal of adsorbed nitrogen atoms, i.e., N(a) + NO(a) → N2O(a) → N2(g) + O(a) and 2N(a) → N2(g), were examined typically on Pd(110). The former takes place in the presence of gaseous CO and shows two-directional N2 desorption collimated far from the surface normal in the normally directed plane along the [001] direction. The latter does not contribute in CO + NO reaction on Pd(110). The model proposed for the inclined desorption was also explained.

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  1. Catalysis Research Center, Hokkaido University, Sapporo, 060-0811, Japan

    Tatsuo Matsushima

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Matsushima, T. Decomposition of Nitrogen Oxides on Palladium and Angle-Resolved Measurements of Desorbing Products. Catalysis Surveys from Asia 5, 71–80 (2002). https://doi.org/10.1023/A:1015116518253

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