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NMR studies of the dynamic behavior of 2-anilino-6-chloro-4-methoxy-1,3,5-triazine in solution

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Abstract

2-Anilino-6-chloro-4-methoxy-1,3,5-triazine was synthesized and studied by dynamic NMR. The activation parameters of hindered internal rotation in unsymmetrically substituted arylamino-sym-triazine were determined for the first time. It was found that a sterically more hindered rotational isomer is thermodynamically more stable in this compound (slow-exchange NOE data).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    P. A. Belyakov & Yu. A. Strelenko

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 18 Institutskii prosp., 142432, Chernogolovka, Moscow Region, Russian Federation

    A. V. Shastin

Authors
  1. P. A. Belyakov
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  2. A. V. Shastin
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  3. Yu. A. Strelenko
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Belyakov, P.A., Shastin, A.V. & Strelenko, Y.A. NMR studies of the dynamic behavior of 2-anilino-6-chloro-4-methoxy-1,3,5-triazine in solution. Russian Chemical Bulletin 50, 2473–2474 (2001). https://doi.org/10.1023/A:1015076722511

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