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Photochromic dihetarylethenes. 10. Photochromic 1,2-bis[2-(benzothiazol-2-yl)-3-thienyl]- and 1,2-bis[2-(benzothiazol-2-yl)benzothiophen-3-yl]ethenes

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Abstract

Dithienylethenes containing the thiophene rings with benzothiazolyl substituents in position 2 were synthesized. 1,2-Bis[2-(benzothiazol-2-yl)benzothiophen-3-yl]hexafluorocyclopentene and 1,2-bis[2,5-di(benzothiazol-2-yl)-3-thienyl]hexafluorocyclopentene possess photochromic properties. The open forms of 1,2-bis(2-benzothiazolylhetaryl)ethenes fluoresce, but introduction of the benzothiazole rings into dihetarylethenes significantly lowers the fatigue resistance of photochromes and favors thermal reversibility.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    M. M. Krayushkin, F. M. Stoyanovich, O. Yu. Zolotarskaya, I. V. Murav"ev & A. Yu. Martynkin

  2. Department of Chemistry, Leninskie Gory, M. V. Lomonosov Moscow State University, 119899, Moscow, Russian Federation

    B. M. Uzhinov

Authors
  1. M. M. Krayushkin
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  2. F. M. Stoyanovich
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  3. O. Yu. Zolotarskaya
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  4. I. V. Murav"ev
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  5. A. Yu. Martynkin
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  6. B. M. Uzhinov
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Krayushkin, M.M., Stoyanovich, F.M., Zolotarskaya, O.Y. et al. Photochromic dihetarylethenes. 10. Photochromic 1,2-bis[2-(benzothiazol-2-yl)-3-thienyl]- and 1,2-bis[2-(benzothiazol-2-yl)benzothiophen-3-yl]ethenes. Russian Chemical Bulletin 50, 2420–2423 (2001). https://doi.org/10.1023/A:1015052017059

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