Abstract
The free volume model is applied to isothermal relaxation and hightemperature creep. For this analysis, the time dependent flow behaviourof Zr55Cu30Al10Ni5 bulk metallic glass (BMG) near the glass transition temperature (T g ) is expressed as a trade off between stress inducedgeneration and diffusion controlled annihilation of free volume. Thestrain rate-stress relation over a wide strain rate-range (10−7to 10−2 s−1) was established for three different temperatures near T g . It was found that the thermal relaxation behaviour and creep kinetics arecontrolled by the mobility of atoms with an activation energy of 161 kJ/mol.
Similar content being viewed by others
References
Busch, R. and Johnson, W.L., ‘The kinetic glass transition of the Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass former-supercooled liquids on a long time scale’, Appl. Phys. Lett. 72, 1998, 2695–2697.
Cohen M.H. and Turnbull, D., ‘Molecular transport in liquids and gasses’, J. Chem. Phys. 31, 1959, 1164–1169.
Duine, P.A., Sietsma, J. and van den Beukel, A., ‘Defect production and annihilation near equilibrium in amorphous Pd40Ni40P20 investigated from viscosity data’, Acta Metall. Mater. 40, 1992, 743–751
Eckert, J., ‘Mechanical alloying of highly processable glassy alloys’, Mater. Sci. Engrg. A226–228, 1997, 364–373.
Ehmler, H., Heesemann, A., Rätzke, K., Faupel, F. and Geyer, U., ‘Mass dependence of diffusion in a supercooled metallic melt’, Phys. Rev. Lett. 80, 1998, 4919–4922.
Faupel, F., ‘Diffusion in non-crystalline metallic and organic media’, Phys. Stat. Sol. (A) 134, 1992, 9–59.
Fielitz, P., Macht, M.-P., Naundorf, V. and Frohberg, G., ‘Diffusion in ZrTiCuNiBe bulk glasses at temperatures around the glass transition’, J. Non-Cryst. Sol. 250–252, 1999, 674–678.
Fulcher, G.S., ‘Analysis of recent measurements of the viscosity of glasses’, J. Amer. Ceram. Soc. 8, 1925, 339–335.
Geyer, U., Schneider, S., Johnson, W.L., Qui, Y., Tombrello, T.A. and Macht, M.-P., ‘Atomic diffusion in the supercooled liquid and glassy states of the Zr41.2Ti13.8Cu12.5Ni10Be22.5 alloy’, Phys. Rev. Lett. 75, 1995, 2364–2367.
Illekova, E., Jergel, M. and Kuhnast, F.-A., ‘On structural and thermal relaxation in non-crystalline Zr-Ni-Al alloys’, Mater. Sci. Engrg. A278, 2000, 27–35.
Inoue, A., Bulk Amorphous Alloys: Preparation and Fundamental Characteristics, Trans Tech Publications, Switzerland, 1998, 68–86.
Leonhard, A., Xing, L.Q., Heilmaier, M., Gebert, A., Eckert, J. and Schultz, L., ‘Effect of crystalline precipitations on the mechanical behavior of bulk glass forming Zr-based alloys’, NanoStruct. Mater. 10, 1998, 805–817.
Lin, X.H. and Johnson, W.L., ‘Formation of Ti-Zr-Cu-Ni bulk metallic glasses’, J. Appl. Phys. 78, 1995, 6514–6519.
Nagel, C., Rätzke, K., Schmidtke, E., Wolff, J., Geyer, U. and Faupel, F., ‘Free-volume changes in the bulk metallic glass Zr46.7Ti8.3Cu7.5Ni10Be27.5 and the undercooled liquid’, Phys. Rev. B 57, 1998, 10224–10227.
Oligschleger, C., Gaukel, C. and Schober, H.R., ‘Relaxation in glasses’, J. Non-Cryst. Solids 250–252, 1999, 660–663.
Reger-Leonhard, A., Heilmaier, M. and Eckert, J., ‘Newtonian flow of Zr55Cu30Al10Ni5 bulk metallic glassy alloys’, Scripta Mater. 43, 2000, 459–464.
Reinker, B., Dopfer, M., Moske, M. and Samwer, K., ‘Specific heat of Zr65Al7.5Cu17.5Ni10 around the glass transition’, Eur. Phys. J. B7, 1999, 359–364.
Russew, K. and Sommer, F., ‘Determination of the viscosity, thermal expansion, heat capacity and bend stress relaxation temperature dependence of glassy alloys-A tool for understanding of relaxation phenomena’, Internat. J. Non-Equilibrium Proc. 11, 1998, 3–23.
Spaepen, F., ‘A microscopic mechanism for steady state inhomogeneous flow in metallic glasses’, Acta Metall. 25, 1977, 407–415.
Taub, A.I., ‘Stress-strain rate dependence of homogeneous flow in metallic glasses’, Acta Metall. 28, 1980, 633–637.
Van Aken, B., De Hey, P. and Sietsma, J., ‘Structural relaxation and plastic flow in amorphous La50Al25Ni25’, Mater. Sci. Engrg. A278, 2000, 247–254.
Van den Beukel, A., ‘On the parameters governing atomic mobility in metallic glasses’, Phys. Stat. Sol. (A) 128, 1991, 285–293.
Van den Beukel, A. and Sietsma, J., ‘The glass transition as a free volume related kinetic phenomenon’, Acta Metall. Mater. 38, 1990, 383–389.
Waniuk, T.A., Busch, R., Masuhr, A. and Johnson, W.L., ‘Equilibrium viscosity of the Zr41.2Ti13.8Cu12.5Ni10Be22.5 bulk metallic glass-forming liquid and viscous flow during relaxation, phase separation, and primary crystallization’, Acta Mater. 46, 1998, 5229–5236.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Daniel, B., Reger-Leonhard, A., Heilmaier, M. et al. Thermal Relaxation and High Temperature Creep of Zr55Cu30Al10Ni5 Bulk Metallic Glass. Mechanics of Time-Dependent Materials 6, 193–206 (2002). https://doi.org/10.1023/A:1015045324786
Issue Date:
DOI: https://doi.org/10.1023/A:1015045324786