Abstract
According to the results of powder X-ray diffraction study of the complex salts of composition [M(NH3)5Cl][M"Cl4] (M = Ir, Rh, or Co and M" = Pt or Pd), the anhydrous salts crystallize in the orthorhombic system (space group Pnma) and are isostructural to the [Ir(NH3)5Cl][PtCl4] complex studied previously. The unit cell parameters of the resulting salts were refined. The metal powders, which were obtained by thermal decomposition of these salts under an atmosphere of hydrogen, were studied by powder X-ray analysis.
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Shubin, Y.V., Korenev, S.V., Yusenko, K.V. et al. Powder X-ray diffraction study of the double complexes [M(NH3)5Cl][M"Cl4] as precursors of metal powders (M = Ir, Rh, Co; M" = Pt, Pd). Russian Chemical Bulletin 51, 41–45 (2002). https://doi.org/10.1023/A:1015045310216
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DOI: https://doi.org/10.1023/A:1015045310216