Skip to main content
SpringerLink
Log in

Synthesis and redox properties of bis-ferrocenylethynyl derivatives of bis(dimethylphosphinoethane)manganese

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Paramagnetic MnII and MnIII complexes containing two ferrocenylethynyl ligands were synthesized. Their redox reactions were studied by cyclic voltammetry and chemical methods. The structures of the resulting compounds were determined by IR, 1H NMR, and ESR spectroscopy. The structure of the complex [(FcC≡C)2Mn(dmpe)2]+PF6 – was established by X-ray diffraction analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. V. Krivykh, I. L. Eremenko, D. Veghini, I. A. Petrunenko, D. L. Pountney, D. Unseld, and H. Berke, J. Organomet. Chem., 1996, 511, 111.

    Google Scholar 

  2. D. Unseld, V. V. Krivykh, K. Heinze, F. Wild, G. Artus, H. Schmalle, and H. Berke, Organometallics, 1999, 18, 1525.

    Google Scholar 

  3. G. S. Girolami and G. Wilkinson, J. Am. Chem. Soc., 1985, 107, 1339.

    Google Scholar 

  4. NMR of Paramagnetic Molecules, Eds. N. La Mar, W. D. Horrocks, and R. H. Holm, Academic Press, New York, 1973.

    Google Scholar 

  5. C. B. Colbert, J. Lewis, N. S. Long, P. R. Raithby, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 1997, 99.

  6. Y. Zhu, O. Clot, M. O. Wolf, and G. P. A. Yap, J. Am. Chem. Soc., 1998, 120, 1812.

    Google Scholar 

  7. D. Jones and M. O. Wolf, Organometallics, 1997, 16, 1352.

    Google Scholar 

  8. C. Lebreton, D. Touchard, L. Pichon, A. Daridor, L. Toupet, and P. H. Dixneuf, Inorg. Chem. Acta, 1998, 272, 188.

    Google Scholar 

  9. C. Levanda, K. Bechaard, and D. O. Cowan, J. Org. Chem., 1976, 41, 2700.

    Google Scholar 

  10. G. Doisneau, G. Balavoine, and T. Fillebeen-Khan, J. Organomet. Chem., 1992, 425, 113.

    Google Scholar 

  11. G. G. Howard, G. S. Girolami, G. Wilkinson, and M. B. Hursthouse, J. Am. Chem. Soc., 1984, 106, 2033.

    Google Scholar 

  12. SMART V5.051 and SAINT V5.00, Area Detector Control and Integration Software, Bruker AXS Inc., Madison, WI-53719, USA, 1998.

  13. G. M. Sheldrick, SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.

    Google Scholar 

  14. G. M. Sheldrick, SHELXTL-97, V5.10, Bruker AXS Inc., Madison, WI-53719, USA, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. G. Belen"kaya, F. M. Dolgushin, M. G. Peterleitner, P. V. Petrovskii & V. V. Krivykh

Authors
  1. A. G. Belen"kaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. M. Dolgushin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. G. Peterleitner
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. V. Petrovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Krivykh
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Belen"kaya, A.G., Dolgushin, F.M., Peterleitner, M.G. et al. Synthesis and redox properties of bis-ferrocenylethynyl derivatives of bis(dimethylphosphinoethane)manganese. Russian Chemical Bulletin 51, 170–174 (2002). https://doi.org/10.1023/A:1015042604281

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1015042604281

Search

Navigation