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Liquid-phase oxidation of thiols with chlorine dioxide

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Abstract

The products and kinetics of the liquid-phase oxidation of 11 aliphatic and aromatic thiols with chlorine dioxide were studied at –10—+70 °C in organic media. The rate constants and activation parameters of the reaction were determined. The influence of the thiol structure on its reactivity was studied. A strong solvent effect on the reaction rate constant was found, and the reaction mechanism was proposed.

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Authors and Affiliations

  1. Institute of Organic Chemistry of the Ufa Scientific Center, Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    M. Z. Yakupov & V. V. Shereshovets

  2. Ufa State Petroleum Technical University, 1 ul. Kosmonavtov, 450062, Ufa, Russian Federation

    U. B. Imashev

  3. Astrakhan State Technological University, 16 ul. Tatishcheva, 414025 Astrakhan, Russian Federation

    F. R. Ismagilov

Authors
  1. M. Z. Yakupov
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  2. V. V. Shereshovets
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  3. U. B. Imashev
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  4. F. R. Ismagilov
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Yakupov, M.Z., Shereshovets, V.V., Imashev, U.B. et al. Liquid-phase oxidation of thiols with chlorine dioxide. Russian Chemical Bulletin 50, 2352–2355 (2001). https://doi.org/10.1023/A:1015023210699

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