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Electrochemical arylation of cobalt and nickel chelates with diphenyliodonium salts

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Abstract

Electrochemical arylation of cobalt chelates with diphenyliodonium salts occurs at low cathodic potentials (viz., potential of the first reduction wave of the diphenyliodonium salt) and affords the phenyl derivatives of CoIII chelates containing the σ-Co—C(sp2) bond. Nickel complexes should be arylated at higher cathodic potentials because it is necessary to generate paramagnetic NiI complexes.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie gory, 119899, Moscow, Russian Federation

    T. V. Magdesieva, D. N. Kravchuk & K. P. Butin

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  1. T. V. Magdesieva
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  2. D. N. Kravchuk
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  3. K. P. Butin
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Magdesieva, T.V., Kravchuk, D.N. & Butin, K.P. Electrochemical arylation of cobalt and nickel chelates with diphenyliodonium salts. Russian Chemical Bulletin 51, 85–89 (2002). https://doi.org/10.1023/A:1015009729780

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