Abstract
The reaction products of Cu(II) 2-chlorobenzoate and the imidazole (1), and of Cu(II) 2,6-dichlorobenzoate and the imidazole (2) formulated as CuL’2⋅2imd⋅2H2O and CuL”2⋅2imd⋅2H2O (L’=C7H4ClO2 −, L”=C7H3Cl2O2 −, imd=imidazole), were prepared and characterized by means of spectroscopic measurements and thermochemical properties. The blue (1) and green (2) complexes were obtained as solids with a 1:2:2 molar ratio of metal to carboxylate ligand to imidazole. When heated at a heating rate of 10 K min−1 the hydrated complexes, (1) and (2), lose some of the crystallization water molecules and then decompose to gaseous products.
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Wołodkiewicz, W. Thermal Decomposition of Cu(II) Complexes with 2-Chloro- and 2,6-Dichlorobenzoic Acid and Imidazole. Journal of Thermal Analysis and Calorimetry 68, 141–146 (2002). https://doi.org/10.1023/A:1014984920421
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DOI: https://doi.org/10.1023/A:1014984920421