Skip to main content
SpringerLink
Log in

Differential Non-Linear Isoconversional Procedure for Evaluating the Activation Energy of Non-Isothermal Reactions

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

A differential isoconversional non-linear procedure for evaluating activation energy from non-isothermal data is suggested. This procedure was applied to model reactions (simulations) and to the dehydration of CaC2O4⋅H2O. The results were compared with those obtained by other isoconversional methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. Paulik, Special Trends in Thermal Analysis, John Wiley & Sons, Chichister, New York, Brisbane, Toronto, Singapore 1995, Ch. 10.

    Google Scholar 

  2. J. Šesták, J. Thermal Anal., 16 (1979) 503.

    Article  Google Scholar 

  3. P. Budrugeac, A. L. Petre and E. Segal, J. Thermal Anal., 47 (1996) 123.

    Article  CAS  Google Scholar 

  4. N. Sbirrazzuoli, Y. Girault and E. Elegant, Thermochim. Acta, 293 (1997) 25.

    Article  CAS  Google Scholar 

  5. C. R. Li and T. B. Tang, J. Materials Sci., 34 (1999) 3467.

    Article  CAS  Google Scholar 

  6. J. M. Criado and J. Morales, Thermochim. Acta, 19 (1977) 305.

    Article  CAS  Google Scholar 

  7. J. M. Criado, J. Morales and V. Rives, J. Thermal Anal., 14 (1978) 221.

    Article  CAS  Google Scholar 

  8. J. M. Criado and A. Ortega, J. Thermal Anal., 29 (1984) 1225.

    Article  CAS  Google Scholar 

  9. Z. Adonyi and G. Körösi, Thermochim. Acta, 60 (1983) 23.

    Article  CAS  Google Scholar 

  10. N. Koga and H. Tanaka, J. Thermal Anal., 37 (1991) 347.

    Article  CAS  Google Scholar 

  11. J. Madarasz, G. Pokol and S. J. Gál, J. Thermal Anal., 42 (1995) 539.

    Google Scholar 

  12. S. Vyazovkin and W. Linert, Intern. Rev. Phys. Chem., 14 (1995) 355.

    Article  CAS  Google Scholar 

  13. S. Bourbigot, R. Delobel, M. Le Bras and D. Normand, J. Chim. Phys., 90 (1993) 1909.

    CAS  Google Scholar 

  14. N. Rose, M. Le Bras, S. Bourbigot and R. Delobel, Polym. Degrad. Stab., 45 (1994) 45.

    Article  Google Scholar 

  15. L. R. Campisi, S. Bourbigot, M. Le Bras and R. Delobel, Thermochim. Acta, 275 (1996) 37.

    Article  Google Scholar 

  16. P. Budrugeac and E. Segal, J. Therm. Anal. Cal., 53 (1998) 269.

    Article  CAS  Google Scholar 

  17. F. J. Gotor, M. Marcias, A. Ortega and J. M. Criado, Int. J. Chem. Kinet., 30 (1998) 647.

    Article  CAS  Google Scholar 

  18. M. E. Brown, M. Maciejewski, S. Vyazovkin, R. Nomen, J. Sempere, A. Burnham, J. Opfermann, R. Strey, H. L. Anderson, A. Kemmler, R. Keuleers, J. Janssens, H. O. Desseyn, C. R. Li, T. B. Tang, B. Roduit, J. Malek and T. Mitsuhashi, Thermochim. Acta, 355 (2000) 125.

    Article  CAS  Google Scholar 

  19. M. Maciejewski, Thermochim. Acta, 355 (2000) 145.

    Article  CAS  Google Scholar 

  20. S. Vyazovkin, Thermochim. Acta, 355 (2000) 155.

    Article  CAS  Google Scholar 

  21. A. K. Burnham, Thermochim. Acta, 355 (2000) 165.

    Article  CAS  Google Scholar 

  22. B. Roduit, Thermochim. Acta, 355 (2000) 171.

    Article  CAS  Google Scholar 

  23. H. Friedman, J. Polym. Sci., 50 (1965) 183.

    Google Scholar 

  24. J. H. Flynn and L. A. Wall, J. Res. Natl. Bur. Stand., A Phys. Chem., 70A (1966) 487.

    Google Scholar 

  25. T. Ozawa, Bull. Chem. Soc. Japan, 38 (1965) 1881.

    Article  CAS  Google Scholar 

  26. T. Akahira and T. Sunose, Res. Report Chiba Inst. Technol. (Sci. Technol.), 16 (1971) 22.

    Google Scholar 

  27. C. R. Li and T. B. Tang, J. Thermal Anal., 49 (1997) 1243.

  28. C. R. Li and T. B. Tang, Thermochim. Acta, 325 (1999) 43.

    Article  CAS  Google Scholar 

  29. S. Vyazovkin and D. Dollimore, J. Chem. Information Comp. Sci., 36 (1996) 42.

    Article  CAS  Google Scholar 

  30. S. Vyazovkin, J. Comput. Chem., 18 (1997) 393.

    Article  CAS  Google Scholar 

  31. S. Vyazovkin, J. Thermal Anal., 49 (1997) 1493.

    Article  CAS  Google Scholar 

  32. G. I. Senum and R. T. Yang, J. Thermal Anal., 16 (1979) 445.

    Google Scholar 

  33. S. Vyazovkin, J. Comput. Chem., 22 (2001) 178.

    Article  CAS  Google Scholar 

  34. E. Urbanovici and E. Segal, Thermochim. Acta, 91 (1985) 373.

    Article  CAS  Google Scholar 

  35. E. Urbanovici and E. Segal, Thermochim. Acta, 94 (1985) 257.

    Article  Google Scholar 

  36. E. Urbanovici and E. Segal, Thermochim. Acta, 95 (1985) 271.

    Article  CAS  Google Scholar 

  37. E. Urbanovici and E. Segal, Thermochim. Acta, 107 (1986) 339.

    Article  CAS  Google Scholar 

  38. C. Popescu, Thermochim. Acta, 285 (1996) 309.

    Article  CAS  Google Scholar 

  39. V. Marcu and E. Segal, Thermochim. Acta, 35 (1980) 43.

    Article  CAS  Google Scholar 

  40. P. Budrugeac, D. Homentcovschi and E. Segal, J. Therm. Anal. Cal., 66 (2001) 557

    Article  CAS  Google Scholar 

  41. P. Budrugeac and E. Segal, J. Materials Sci., 36 (2001) 2707.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Research and Development Institute for Electrical Engineering, ICPE-CA, Splaiul Unirii 313, Sector 3, Bucharest, 74204, Romania

    P. Budrugeac

Authors
  1. P. Budrugeac
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Budrugeac, P. Differential Non-Linear Isoconversional Procedure for Evaluating the Activation Energy of Non-Isothermal Reactions. Journal of Thermal Analysis and Calorimetry 68, 131–139 (2002). https://doi.org/10.1023/A:1014932903582

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1014932903582

Search

Navigation