Abstract
The addition of triethylsilane to O- and S- heterocyclic Schiff bases in the presence of Rh, Pd, Pt, and Ir complexes has been studied. A series of the corresponding amines has been synthesized using the most active catalysts, which were the dimeric, monovalent complexes [Rh(1,5-cyclooctadiene)Cl]2 and [Pd(allyl)Cl]2.
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Iovel, I., Golomba, L., Popelis, J. et al. Hydrosilylation Of Heterocyclic Aldimines Catalyzed By Transition Metal Complexes. Chemistry of Heterocyclic Compounds 38, 46–53 (2002). https://doi.org/10.1023/A:1014899124792
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DOI: https://doi.org/10.1023/A:1014899124792