Abstract
The possibility of using SPARK-1M spectrometer for studying the shift of emission lines belonging to the K series of X-ray spectra of transition metals (chemical shift of the lines) was studied. The possibility of using the spectrometer for measuring the chemical shift and evaluating the relative amounts of transition metals in different oxidation states is analyzed.
Similar content being viewed by others
REFERENCES
Brytov, I.A., Obolenskii, E.A., Gol'denberg, M.S., et al., in Apparatura i metody rentgenovskogo analiza (Apparatus and Methods of X-ray Analysis), Leningrad: Mashinostroenie, 1983, issue 29, pp. 14-18.
Blokhin, M.A. and Nikiforov, I.Ya., in Apparatura i metody rentgenovskogo analiza (Apparatus and Methods of X-ray Analysis), Leningrad: Mashinostroenie, 1972, issue 10, pp. 89-94.
Li, Z., Ruqin, Y., Shi, L., and Wang, Q., Anal. Chim. Acta, 1991, vol. 248, no. 1, pp. 257-261.
Terada, S., Shikamori, Y., Fukushima, S., et al., J. Trace Microprobe Tech., 1989, vol. 7, nos. 1–2, pp. 31-45.
Pinkerton, A., Norrish, K., and Randall, P.J., X-ray Spectrom., 1990, vol. 19, no. 2, pp. 63-65.
Hoffer, H.E., Brey, G.P., Schulz-Dobrick, B., and Oberhansli, R., Eur J. Mineral., 1994, vol. 6, pp. 407-418.
Jshima, M., Anal. Sci., 1998, vol. 14, no. 6, pp. 1139-1144.
Kalinin, B.D. and Plotnikov, R.I., Zavod. Lab., 1998, vol. 64, no. 9, pp. 29-32.
Kalinin, B.D., Karamyshev, N.I., Plotnikov, R.I., et al., Zavod. Lab., 1998, vol. 64, no. 2, pp. 15-19.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kalinin, B.D., Plotnikov, R.I. & Kostikov, Y.P. On the Possibility of Using SPARK-1M Portable X-ray Spectrometer for Studying the Chemical Bond. Russian Journal of Applied Chemistry 74, 1884–1887 (2001). https://doi.org/10.1023/A:1014896812245
Issue Date:
DOI: https://doi.org/10.1023/A:1014896812245