Abstract
Solubilities are reported for the tris-ligand–iron(III) complexes of 3-hydroxy-2-ethyl-4-pyranone and of 3-hydroxy-1,2-dimethyl-4-pyridinone in aqueous solutions of alkali halides and of ammonium and tetraalkylammonium bromides. The Setchenow coefficients estimated from salt effects on solubilities for these complexes are compared with those for other inorganic complexes.
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References
M.L. Tobe and J. Burgess, Inorganic Reaction Mechanisms, Addison-Wesley-Longman, Harlow, 1999, Ch. 8; and references therein.
M.J. Blandamer and J. Burgess, Transition Met. Chem., 13, 1 (1988); and references therein.
J. Setchenow, Z. Phys. Chem., 4, 117 (1889); Ann. Chim., 25, 226 (1892).
M. Kofler, Phys. Z., 9, 6 (1908).
F.A. Long and W.F. McDevit, Chem. Rev., 51, 119 (1952).
V.F. Sergeeva, Russ. Chem. Rev., 34, 309 (1965).
C.V. Krishnan and H.L. Friedman, J. Solution Chem., 3, 727 (1974).
M.J. Blandamer, J. Burgess and P.P. Duce, J. Inorg. Nucl. Chem., 43, 3103 (1981).
W.L. Masterton, D. Bolocofsky and T.P. Lee, J. Phys. Chem., 75, 2809 (1971).
P. Perez-Tejeda, A. Maestre, P. Delgado-Cobos and J. Burgess, Can. J. Chem., 68, 243 (1990).
J.N. Brønsted, J. Am. Chem. Soc., 44, 939 (1922); J.N. Brønsted, A. Delbanco and K. Volqvarts, Z. Phys. Chem., 162, 128 (1932).
M.J. Blandamer, J. Burgess and J.C. McGowan, J. Chem. Soc., Dalton Trans., 616 (1980).
M.J. Blandamer, J. Burgess and P.P. Duce, Transition Met. Chem., 8, 308 (1983).
R.C. Hider and A.D. Hall, Progr. Med. Chem., 28, 41 (1991).
R.C. Hider, G. Kontoghiorghes, J. Silver and M.A. Stockham, UK Patent Application GB 2 136 806A (1984); R.C. Hider, G. Kontoghiorghes and M.A. Stockham, European Patent Application 0 107 458 (1984); G.J. Kontoghiorghes, Ann. N. Y. Acad. Sci., 612, 339 (1990); G.J. Kontoghiorghes, A.N. Bartlett, A.V. Ho.brand, J.G. Goddard, L. Sheppard, J. Barr and P. Nortey, Brit. J. Haematol., 76, 295 (1990); G.J. Kontoghiorghes, J.G. Goddard, A.N. Bartlett and L. Sheppard, Clin. Pharmacol. Ther., 48, 255 (1990); R.C. Hider and A.D. Hall, Perspect. Bioinorg. Chem., 1, 209 (1991); G.J. Kontoghiorghes, Analyst, 120, 845 (1995).
S. Alshehri, J. Burgess, K.A. Darcey and M.S. Patel, Transition Met. Chem., 19, 119 (1994).
S. Ahmad, J. Burgess, G. Capper, N.C. Fellowes and M.S. Patel, Polyhedron, 12, 1145 (1993).
J. Burgess and M.S. Patel, Inorg. Chim. Acta, 170, 241 (1990).
E. Beatty, J. Burgess and M.S. Patel, Can. J. Chem., 72, 1370 (1994).
E. Beatty, J. Burgess and M.S. Patel, J. Inorg. Biochem., 43, 487 (1991).
S. Ahmed, J. Burgess, B. Hurman and S.A. Parsons, Polyhedron, 13, 23 (1994).
M.M. Finnegan, S.J. Rettig and C. Orvig, J. Am. Chem. Soc., 108, 5033 (1986).
W.C. Griffin, J. Soc. Cosmet. Chem., 1, 311 (1946); 5, 249 (1954); R.F. Rekker and R. Mannhold (Eds), Calculation of Drug Lipophilicity, VCH, Weinheim, 1992.
J.B. Porter, M. Gyparaki, L.C. Burke, E.R. Huehns, P. Sarpong, V. Saez and R.C. Hider, Blood, 72, 1497 (1988).
A. Tapparo and M. Perazzolo, Int. J. Environ. Anal. Chem., 36, 13 (1989); M.S. Patel, Ph.D. Thesis, Leicester, 1992.
R.D. Gillard and M.M. Shoukry, Polyhedron, 14, 757 (1995).
I.M. Koltho. and G.M. Sandell, Textbook of Quantitative Inorganic Analysis, 3rd edit., Macmillan, New York, 1952, pp. 303-304; A.I. Vogel, Textbook of Quantitative Inorganic Analysis, 3rd edit., Longman, London, 1961, p. 18; D.C. Harris, Quantitative Chemical Analysis, Freeman, San Francisco, 1982, pp. 82-83, 89-90; D.A. Skoog, D.M. West and F.J. Holler, Fundamentals of Analytical Chemistry, 7th edit., Saunders, Philadelphia, 1996, pp. 148-150.
M.A. PaulJ. Am. Chem. Soc., 74, 5274 (1952); F.A Long and R.L. Bergen, J. Phys. Chem., 60, 1131 (1956); N.C. Deno and C.H. Spink, J. Phys. Chem., 67, 1347 (1963).
M. Balon, A. Maestre, E. Muñoz de Miguel and E. Soria del Hoyo, Can. J. Chem., 61, 244 (1983).
T.J. Morrison and N.B.B. Johnstone, J. Chem. Soc., 3655 (1955).
P. Debye and J. McAulay, Phys. Z., 26, 22 (1925); B.E. Conway, J.E. Desnoyers and A.C. Smith, Phil. Trans. Roy. Soc. London, A256, 389 (1964).
J.O'M. Bockris, J. Bowler-Reed and J.A. Kitchener, Trans. Faraday Soc., 47, 184 (1951).
F.A. Long and W.F. McDevit, J. Am. Chem. Soc., 74, 1773 (1952).
W.L. Masterton and T.P. Lee, J. Phys. Chem., 74, 1776 (1970); M. Fromon and C. Treiner, J. Chem. Soc., Faraday Trans. I, 75, 1837 (1979); and references therein.
J.C. McGowan and A. Mellors, Molecular Volumes in Chemistry and Biology, Ellis Horwood, Chichester, 1986, Ch. 5.
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Lu, ZS., Burgess, J. & Lane, R. Solubilities of iron(III) complexes of 3-hydroxy-2-ethyl-4-pyranone and of 3-hydroxy-1,2-dimethyl-4-pyridinone in aqueous salt solutions. Transition Metal Chemistry 27, 239–243 (2002). https://doi.org/10.1023/A:1014823509354
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DOI: https://doi.org/10.1023/A:1014823509354