Skip to main content
Log in

Organotin Compounds in Sediments from the Göta älv Estuary

  • Published:
Water, Air, and Soil Pollution Aims and scope Submit manuscript

Abstract

Concentrations of organotin compounds in sediments from four sites in the Göta älv estuary, SW Sweden, rangefrom 17 to 366 ng/g dw for tributyltin (TBT) and from1.5 to 71 ng/g dw for triphenyltin (TPT), similar toresults from other harbours and marinas and from an earlier study in the Göteborg Harbour, which is located in the estuary. Also dibutyltin, monobutyltin, diphenyltin and monophenyltin, the degradation products of TBT and TPT, werefound. TBT concentrations are the highest in the inner harbour and in the upper sediment layer of ca. 10 cm, indicating the risk for mobilisation of TBT bound in surface sediments in thefrequently disturbed harbour environment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Alzieu, C., Sanjua, J., Deltriel, J. P. and Borel, M.: 1986, ‘Tin Contamination in Arcachon Bay: Effects on Oyster Shell Anomalies’, Mar. Pollut. Bull. 17, 494–498.

    Google Scholar 

  • Biselli, S., Bester, K., Hühnerfuss, H. and Fent, K.: 2000, ‘Concentrations of the Antifouling Compound Irgarol 1051 and of Organitins in Water and Sediments of the German North and Baltic Sea Marinas’, Mar. Pollut. Bull. 40(3), 233–243.

    Google Scholar 

  • Brack, K., Stevens, R. L. and Paetzel, M.: 2000, ‘Holocene environmental change and the accumulation-erosion balance of sheltered river-mouth sediments. Göteborg, SW Sweden’, Mar. Geol. 170(3–4), 347–362.

    Google Scholar 

  • Carter, R. J., Turoczy, N. J. and Bond, A. M.: 1989, ‘Container adsorption of tributyltin (TBT) compounds: implications for environmental analysis’, Environ. Sci. Technol. 23, 615–617.

    Google Scholar 

  • Cato, I.: 1992, ‘Sedimentological Investigations of the Bohus Coast 1990 – the Coastal Water Monitoring Program of the Göteborg and Bohus County’, Sveriges Geologiska Undersökning 74, Uppsala, 97 pp.

  • Ceulemans, M., Lobinski, R., Dirkx, W. M. R. and Adams, F. C.: 1993, ‘Rapid sensitive speciation analysis of butyl-and phenyltin compounds in water by capillary gas chromatography atomic emission spectrometry (GC-AES) after in-situ ethylation and in-liner preconcentration’, Fresenius J. Anal. Chem. 347, 256–262.

    Google Scholar 

  • Dahllöf, I.: 1998, ‘On the Impact of TBT on Marine Sediment Systems as Assessed by Biogeochemical Effect Indicators’, Ph.D. Thesis, Department of Analytical and Marine Chemistry, Göteborg University, 30 pp.

  • Dela Cruz, M. A. T. and Molander, S.: 1998, ‘Butyltins in marine sediments from the Swedish West Coast' Report 1998: 1, Department of Technical Environmental Planning, Chalmers University of Technology, Göteborg, Sweden, 14 pp.

    Google Scholar 

  • Dowson, P. H., Bubb, J. M. and Lester, J. N.: 1993a, ‘Temporal distribution of organotins in the aquatic environment: Five years after the 1987 U.K. Retail Ban on TBT-based antifouling paints’, Mar. Pollut. Bull. 26(9), 487–494.

    Google Scholar 

  • Dowson, P. H., Bubb, J. M., Williams, T. P. and Lester, J. N.: 1993b, ‘Degradation of tributyltin in freshwater and estuarine marine sediments’, Water Sci. Technol. 28(8–9), 133–137.

    Google Scholar 

  • Engström, L. T. and Stevens R. L.: 1999, ‘Multiparameter Normalisation of Geochemical Data from Göteborg Harbour’, in G. De Schutter (ed.), Proceedings of the 4th International Conference on Characterisation and Treatment of Sediments, Antwerpen, Belgium, September 1999, pp. 159–168.

  • Evans, S. M., Birchenough, A. C. and Brancato, M. S.: 2000, ‘The TBT Ban: Out of the Frying Pan into the Fire?’, Mar. Pollut. Bull. 40(3), 204–211.

    Google Scholar 

  • Fent, K., Hunn., J., Renggli, D. and Siegrist, H.: 1991, ‘Fate of tributyltin in sewage sludge treatment’, Mar. Env. Res. 32, 223–231.

    Google Scholar 

  • Fent, K. and Meier, W.: 1994, ‘Effects of triphenyltin on fish early life stages’, Arch. Env. Contamin. Toxicol. 27(2), 224–231.

    Google Scholar 

  • Følsvik, N., Berge, J. A., Brevik, E. M. and Walday, M.: 1999, ‘Quantification of organotin com-pounds and determination of imposex in populations of dogwhelks (Nucella lapillus) from Norway’, Chemosphere 38(3), 681–691.

    Google Scholar 

  • Harino, H., Fukushima, M., Kurokawa, Y. and Kawai, S.: 1997, ‘Degradation of the tributyltin compounds by the microorganisms in water and sediment collected from the harbour area of Osaka City, Japan’, Env. Poll. 98(2), 163–167.

    Google Scholar 

  • Harino, H., Fukushima, M., Yamamoto, Y., Kawai, S. and Miyazaki, N.: 1998, ‘Contamination of butylin and phenyltin compounds in the marine environment of Otsuchi Bay, Japan’, Env. Poll. 101, 209–214.

    Google Scholar 

  • Kuballa, J., Wilken, R.-D., Jantzen, E., Kwan, K. K. and Chau, Y. K.: 1995, ‘Speciation and genotoxicity of butyltin compounds’, Analyst 120, 667–674.

    Google Scholar 

  • Langston, W. J. and Pope, N. D.: 1995, ‘Determinants of TBT Adsorption and Desorption in Estuarine Sediments’, Mar. Pollut. Bull. 31(1–3), 32–43.

    Google Scholar 

  • Ma, H., Dai, S. and Huang, G.: 2000, ‘Distribution of tributyltin chloride in laboratory simulated estuarine microcosms’, Water Res. 34(10), 2829–2841.

    Google Scholar 

  • Meador, J. P., Krone, C. A., Dyer, D. W. and Varanasi, U.: 1997, ‘Toxicity of sediment-associated tributyltin to infaunal invertebrates: Species comparison and the role of organic carbon’, Mar. Envir. Res. 43(3), 219–241.

    Google Scholar 

  • OSPAR: 1996, ‘Report of the Third OSPAR Workshop on Ecotoxicological Assessment Criteria’, Den Haag, November 1996. Oslo-Paris Commission for the Protection of the Marine Environment of the North-East Atlantic.

  • Pereira, W. E., Wade, T. L., Hostettler, F. D. and Parchaso, F.: 1999, ‘Accumulation of Butyltins in Sediments and Lipid Tissues of the Asian Clam, Potomocorbula amurensis, Near Mare Island Naval Shipyard, San Francisco Bay’, Mar. Pollut. Bull. 38(11), 1005–1010.

    Google Scholar 

  • Shim, W. J., Oh, J. R., Kanhg, S. H., Shim, J. H. and Lee, S. H.: 1999, ‘Horizontal distribution of butyltins in surface sediments from an enclosed bay system, Korea’, Env. Poll. 106, 351–357.

    Google Scholar 

  • Stuer-Lauridsen, F. and Dahl, B.: 1995, ‘Source of organotin at a marine water/sediment interface – A field study’, Chemosphere 30(5), 831–845.

    Google Scholar 

  • Thompson, J. A. J., Sheffer, M. G., Pierce, R. C., Chau, Y. K., Cooney, J. J., Cullen, W. P. and Maguire, R. J.: 1985, ‘Organotin Compounds in the Aquatic Environment: Scientific Criteria for Assessing Their Effects on Environmental Quality’, National Research Council Canada Series No. 22494, Ottawa, Canada, 284 pp.

  • Wilken, R. D., Kuballa, J. and Jantzen, E.: 1994, ‘Organotins: their analysis and assessment in the Elbe river system, Northern Germany’, Fresenius J. Analyt. Chem. 350, 77–84.

    Google Scholar 

  • Yonanzawa, Y., Fukui, M., Yoshida, T., Ochi, A., Tanaka, T., Noguti, Y., Kowata, T., Sato, Y., Masanuga, S. and Urushigawa, Y.: 1994, ‘Degradation of tri-n-butyltin in Ise Bay sediment’, Chemosphere 29(6), 1349–1356.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Karin Brack.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Brack, K. Organotin Compounds in Sediments from the Göta älv Estuary. Water, Air, & Soil Pollution 135, 131–140 (2002). https://doi.org/10.1023/A:1014776425790

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1014776425790

Navigation