Abstract
Concentrations of organotin compounds in sediments from four sites in the Göta älv estuary, SW Sweden, rangefrom 17 to 366 ng/g dw for tributyltin (TBT) and from1.5 to 71 ng/g dw for triphenyltin (TPT), similar toresults from other harbours and marinas and from an earlier study in the Göteborg Harbour, which is located in the estuary. Also dibutyltin, monobutyltin, diphenyltin and monophenyltin, the degradation products of TBT and TPT, werefound. TBT concentrations are the highest in the inner harbour and in the upper sediment layer of ca. 10 cm, indicating the risk for mobilisation of TBT bound in surface sediments in thefrequently disturbed harbour environment.
Similar content being viewed by others
References
Alzieu, C., Sanjua, J., Deltriel, J. P. and Borel, M.: 1986, ‘Tin Contamination in Arcachon Bay: Effects on Oyster Shell Anomalies’, Mar. Pollut. Bull. 17, 494–498.
Biselli, S., Bester, K., Hühnerfuss, H. and Fent, K.: 2000, ‘Concentrations of the Antifouling Compound Irgarol 1051 and of Organitins in Water and Sediments of the German North and Baltic Sea Marinas’, Mar. Pollut. Bull. 40(3), 233–243.
Brack, K., Stevens, R. L. and Paetzel, M.: 2000, ‘Holocene environmental change and the accumulation-erosion balance of sheltered river-mouth sediments. Göteborg, SW Sweden’, Mar. Geol. 170(3–4), 347–362.
Carter, R. J., Turoczy, N. J. and Bond, A. M.: 1989, ‘Container adsorption of tributyltin (TBT) compounds: implications for environmental analysis’, Environ. Sci. Technol. 23, 615–617.
Cato, I.: 1992, ‘Sedimentological Investigations of the Bohus Coast 1990 – the Coastal Water Monitoring Program of the Göteborg and Bohus County’, Sveriges Geologiska Undersökning 74, Uppsala, 97 pp.
Ceulemans, M., Lobinski, R., Dirkx, W. M. R. and Adams, F. C.: 1993, ‘Rapid sensitive speciation analysis of butyl-and phenyltin compounds in water by capillary gas chromatography atomic emission spectrometry (GC-AES) after in-situ ethylation and in-liner preconcentration’, Fresenius J. Anal. Chem. 347, 256–262.
Dahllöf, I.: 1998, ‘On the Impact of TBT on Marine Sediment Systems as Assessed by Biogeochemical Effect Indicators’, Ph.D. Thesis, Department of Analytical and Marine Chemistry, Göteborg University, 30 pp.
Dela Cruz, M. A. T. and Molander, S.: 1998, ‘Butyltins in marine sediments from the Swedish West Coast' Report 1998: 1, Department of Technical Environmental Planning, Chalmers University of Technology, Göteborg, Sweden, 14 pp.
Dowson, P. H., Bubb, J. M. and Lester, J. N.: 1993a, ‘Temporal distribution of organotins in the aquatic environment: Five years after the 1987 U.K. Retail Ban on TBT-based antifouling paints’, Mar. Pollut. Bull. 26(9), 487–494.
Dowson, P. H., Bubb, J. M., Williams, T. P. and Lester, J. N.: 1993b, ‘Degradation of tributyltin in freshwater and estuarine marine sediments’, Water Sci. Technol. 28(8–9), 133–137.
Engström, L. T. and Stevens R. L.: 1999, ‘Multiparameter Normalisation of Geochemical Data from Göteborg Harbour’, in G. De Schutter (ed.), Proceedings of the 4th International Conference on Characterisation and Treatment of Sediments, Antwerpen, Belgium, September 1999, pp. 159–168.
Evans, S. M., Birchenough, A. C. and Brancato, M. S.: 2000, ‘The TBT Ban: Out of the Frying Pan into the Fire?’, Mar. Pollut. Bull. 40(3), 204–211.
Fent, K., Hunn., J., Renggli, D. and Siegrist, H.: 1991, ‘Fate of tributyltin in sewage sludge treatment’, Mar. Env. Res. 32, 223–231.
Fent, K. and Meier, W.: 1994, ‘Effects of triphenyltin on fish early life stages’, Arch. Env. Contamin. Toxicol. 27(2), 224–231.
Følsvik, N., Berge, J. A., Brevik, E. M. and Walday, M.: 1999, ‘Quantification of organotin com-pounds and determination of imposex in populations of dogwhelks (Nucella lapillus) from Norway’, Chemosphere 38(3), 681–691.
Harino, H., Fukushima, M., Kurokawa, Y. and Kawai, S.: 1997, ‘Degradation of the tributyltin compounds by the microorganisms in water and sediment collected from the harbour area of Osaka City, Japan’, Env. Poll. 98(2), 163–167.
Harino, H., Fukushima, M., Yamamoto, Y., Kawai, S. and Miyazaki, N.: 1998, ‘Contamination of butylin and phenyltin compounds in the marine environment of Otsuchi Bay, Japan’, Env. Poll. 101, 209–214.
Kuballa, J., Wilken, R.-D., Jantzen, E., Kwan, K. K. and Chau, Y. K.: 1995, ‘Speciation and genotoxicity of butyltin compounds’, Analyst 120, 667–674.
Langston, W. J. and Pope, N. D.: 1995, ‘Determinants of TBT Adsorption and Desorption in Estuarine Sediments’, Mar. Pollut. Bull. 31(1–3), 32–43.
Ma, H., Dai, S. and Huang, G.: 2000, ‘Distribution of tributyltin chloride in laboratory simulated estuarine microcosms’, Water Res. 34(10), 2829–2841.
Meador, J. P., Krone, C. A., Dyer, D. W. and Varanasi, U.: 1997, ‘Toxicity of sediment-associated tributyltin to infaunal invertebrates: Species comparison and the role of organic carbon’, Mar. Envir. Res. 43(3), 219–241.
OSPAR: 1996, ‘Report of the Third OSPAR Workshop on Ecotoxicological Assessment Criteria’, Den Haag, November 1996. Oslo-Paris Commission for the Protection of the Marine Environment of the North-East Atlantic.
Pereira, W. E., Wade, T. L., Hostettler, F. D. and Parchaso, F.: 1999, ‘Accumulation of Butyltins in Sediments and Lipid Tissues of the Asian Clam, Potomocorbula amurensis, Near Mare Island Naval Shipyard, San Francisco Bay’, Mar. Pollut. Bull. 38(11), 1005–1010.
Shim, W. J., Oh, J. R., Kanhg, S. H., Shim, J. H. and Lee, S. H.: 1999, ‘Horizontal distribution of butyltins in surface sediments from an enclosed bay system, Korea’, Env. Poll. 106, 351–357.
Stuer-Lauridsen, F. and Dahl, B.: 1995, ‘Source of organotin at a marine water/sediment interface – A field study’, Chemosphere 30(5), 831–845.
Thompson, J. A. J., Sheffer, M. G., Pierce, R. C., Chau, Y. K., Cooney, J. J., Cullen, W. P. and Maguire, R. J.: 1985, ‘Organotin Compounds in the Aquatic Environment: Scientific Criteria for Assessing Their Effects on Environmental Quality’, National Research Council Canada Series No. 22494, Ottawa, Canada, 284 pp.
Wilken, R. D., Kuballa, J. and Jantzen, E.: 1994, ‘Organotins: their analysis and assessment in the Elbe river system, Northern Germany’, Fresenius J. Analyt. Chem. 350, 77–84.
Yonanzawa, Y., Fukui, M., Yoshida, T., Ochi, A., Tanaka, T., Noguti, Y., Kowata, T., Sato, Y., Masanuga, S. and Urushigawa, Y.: 1994, ‘Degradation of tri-n-butyltin in Ise Bay sediment’, Chemosphere 29(6), 1349–1356.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Brack, K. Organotin Compounds in Sediments from the Göta älv Estuary. Water, Air, & Soil Pollution 135, 131–140 (2002). https://doi.org/10.1023/A:1014776425790
Issue Date:
DOI: https://doi.org/10.1023/A:1014776425790