Abstract
A universal approach to the synthesis of juvenoid hydroprene and methoprene was developed on the basis of monoalkylation of acetoacetate by 1-acetoxy-5-bromo-3-methylpentane, the product of acidic decyclization of 4-methyltetrahydropyran.
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Ishmuratov, G.Y., Yakovleva, M.P., Galyautdinova, A.V. et al. UNIVERSAL APPROACH TO THE SYNTHESIS OF JUVENOID HYDROPRENE AND METHOPRENE FROM 4-METHYLTETRAHYDROPYRAN. Chemistry of Natural Compounds 37, 486–489 (2001). https://doi.org/10.1023/A:1014439914429
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DOI: https://doi.org/10.1023/A:1014439914429