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MODELLING TRANSANNULAR CYCLIZATION OF 1(10)E,4E-GERMACRANOLIDE COSTUNOLIDE INTO EUDESMANE DERIVATIVES

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Abstract

Semi-empirical quantum-chemical methods were used to model transannular cyclization of 1(10)E,4E-germacranolide costunolide into eudesmanolides. The conformational states favorable for the transformation and the energy barriers were calculated.

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Authors and Affiliations

  1. Institute of Phytochemistry, Ministry of Education and Science of the Republic of Kazakhstan, Karaganda

    B. B. Khasenov & K. M. Turdybekov

Authors
  1. B. B. Khasenov
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  2. K. M. Turdybekov
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Khasenov, B.B., Turdybekov, K.M. MODELLING TRANSANNULAR CYCLIZATION OF 1(10)E,4E-GERMACRANOLIDE COSTUNOLIDE INTO EUDESMANE DERIVATIVES. Chemistry of Natural Compounds 37, 451–454 (2001). https://doi.org/10.1023/A:1014423510794

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  • DOI: https://doi.org/10.1023/A:1014423510794

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