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Organic/inorganic hybrid compound: α-Dodecamolybdophosphoric acid–3-(4,5-diazafluoren-one)-3–water

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Abstract

In the title compound (C11H6N2O)3·H3PMo12O40·3H2O(1), the α-dodecamolybdophosphoric acid residue has the Keggin structure, with M–O distance ranging between 1.673(5) and 2.464(4) Å. The water molecules are involved in O–H···N and O–H···O intermolecular hydrogen bonds with the diazafluoren moiety and α-dodecamolybdophosphoric acid respectively while the diazafluoren moiety and α-dodecamolybdophosphoric acid are connected through C–H···O interactions. The O–H···O intermolecular hydrogen bonds form infinite chains of Mo12O40 units in which N···O contacts interconnect the chains to form layers.

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Authors and Affiliations

  1. X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia

    Ibrahim Abdul Razak, S. Shanmuga Sundara Raj & Hoong-Kun Fun

  2. Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, 90112, Thailand

    Suchada Chantrapromma

  3. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, People's Republic of China

    Yun-Shan Zhou & Xiao-Zeng You

Authors
  1. Ibrahim Abdul Razak
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  2. S. Shanmuga Sundara Raj
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  3. Suchada Chantrapromma
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  4. Hoong-Kun Fun
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  5. Yun-Shan Zhou
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  6. Xiao-Zeng You
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Razak, I.A., Raj, S.S.S., Chantrapromma, S. et al. Organic/inorganic hybrid compound: α-Dodecamolybdophosphoric acid–3-(4,5-diazafluoren-one)-3–water. Journal of Chemical Crystallography 31, 255–262 (2001). https://doi.org/10.1023/A:1014370427299

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  • DOI: https://doi.org/10.1023/A:1014370427299

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