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Structure and characterization of bis(N-p-chloro-phenyl-salicylideneaminate) Schiff base copper(II) complex: Cu[N-p-Cl-Ph-Sal]2

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Abstract

The crystal and molecular structure of the title compound has been determined by X-ray crystallography. It crystallizes in the monoclinic system, space group P21/c, with lattice parameters a = 13.678(3), b = 10.729(2), c = 8.1996(2) Å, β = 98.96°, V = 1188.7(4) Å3, and Z = 4. The crystal structure contains two centrosymmetric molecules of bis (N-p-chloro-phenyl-salicylideneaminate) Schiff base copper(II). Copper(II) ion is coordinated in a slightly distorted trans square-planar configuration, the distortion consisting of a reduction of the N–Cu–O angle with the chelate rings from the ideal value of 90°. The p-chlorophenyl rings with salicylidene moieties form a dihedral angle of 38.96°.

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References

  1. Holm, R.H.; Everett, G.W., Jr.; Chakravorty, A. Progr. Inorg. Chem. 1966, 7, 83.

    Google Scholar 

  2. Kovacic, J.E. Spectrochim. Acta. Sect. A 1967, 23, 183.

    Google Scholar 

  3. Zheng, Z.; Han, M.; Chen, H.L. Chin. Chem. Lett. 1996, 7(8), 739.

    Google Scholar 

  4. Mazaletskii, A.B.; Vinogradova, V.G. Res. Chem. Kinet. 1995, 53.

  5. Sheldrick, G.M. SADABS, Program for Empirical Absorption Correction of Area Detector Data; University of Gottingen: Germany, 1996.

    Google Scholar 

  6. Sheldrick, G.M. SHELXTL V5, Reference Manual; Siemens Analytical X-ray Sysytems, Inc.: Madison, WI, 1996.

    Google Scholar 

  7. Wilson, A.J.C. International Table for X-ray Crystallography, Kluwer Academic Publisher: Dordrecht, 1992; Vol. C, Table 6.1.1.4 (pp 500-502) and 4.2.6.8 (pp 219-222) respectively.

    Google Scholar 

  8. Takeuchi, A.; Kuma, H.; Yamada, S. Synth. React. Inorg. Met.-Org. Chem. 1994, 24(2), 171.

    Google Scholar 

  9. Tamura, H.; Ogawa, K.; Takeuchi, A.; Yamada, S. Chem. Lett. 1977, 899.

  10. Yamada, S.; Takeuchi, A. Coord. Chem. Rev. 1982, 43, 187.

    Google Scholar 

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Authors and Affiliations

  1. Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing, 210094, People's Republic of China

    Qiaofeng Han, Fangfang Jian, Lude Lu, Xujie Yang & Xin Wang

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  1. Qiaofeng Han
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  2. Fangfang Jian
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  3. Lude Lu
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  4. Xujie Yang
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  5. Xin Wang
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Han, Q., Jian, F., Lu, L. et al. Structure and characterization of bis(N-p-chloro-phenyl-salicylideneaminate) Schiff base copper(II) complex: Cu[N-p-Cl-Ph-Sal]2. Journal of Chemical Crystallography 31, 247–250 (2001). https://doi.org/10.1023/A:1014366326391

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