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A novel four-coordinate zinc(II) complex of the di-N-hydroxypropylated tetraaza macrocycle

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Abstract

The compound [Zn(L2)Cl]ClO4·H2O (1) (L2 = 2,13,-bis(3-hydroxypropyl)-5,16-di-methyl-2,6,13,17-tetraazatricyclo[14,4,01.18,07.12]docosane) has been synthesized and structurally characterized. 1 crystallizes in the monoclinic system, space group P21/c with a = 8.932(2), b = 16.189(2), c = 22.492(4) Å β = 95.34(2)° V = 3238.3(11) Å3; and Z = 4. The zinc atom is placed in a highly distorted tetrahedral environment bonding with three nitrogen atoms of the macrocycle and one chlorine atom.

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Authors and Affiliations

  1. Department of Cultural Heritage Conservation Science, Kongju National University, Kongju, 314-701, South Korea

    Ki-Young Choi

  2. Taejon Daeshin High School, Taejon, 302-210, South Korea

    Yong-Man Jeon

  3. Department of Chemical Education, Kongju National University, Kongju, 314-701, South Korea

    Choon Pyo Hong & Haiil Ryu

  4. Department of Physics, Chungnam National University, Taejon, 305-764, South Korea

    Il-Hwan Suh

Authors
  1. Ki-Young Choi
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  2. Yong-Man Jeon
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  3. Choon Pyo Hong
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  4. Haiil Ryu
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  5. Il-Hwan Suh
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Choi, KY., Jeon, YM., Hong, C.P. et al. A novel four-coordinate zinc(II) complex of the di-N-hydroxypropylated tetraaza macrocycle. Journal of Chemical Crystallography 31, 197–201 (2001). https://doi.org/10.1023/A:1014343115913

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  • DOI: https://doi.org/10.1023/A:1014343115913

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