Abstract
Four nickle(II) 1,5-naphthalenedisulfonate (1,5nds) complexes, namely [Ni(H2O)6] (1,5nds) (1), trans-[Ni(en)2(H2O)2](1,5nds)·2H2O (2), [Ni(tren)(H2O)2](1,5nds)·H2O (3), and [Ni(dien)2](1,5nds)·2H2O (4), where en = ethylenediamine, tren = tris(2-aminoethyl)amine, and dien = diethylenetriamine, have been synthesized and structurally characterized. Compound 1 crystallizes in space group P21/c, with a = 13.200(2) Å, b = 6.6197(10) Å, c = 9.6001(14) Å, and β = 92.005(3)° compound 2 crystallizes in space group C2/c, with a = 15.698(2) Å, b = 13.006(2) Å, c = 12.845(2) Å, and β = 119.262(4) Å compound 3 crystallizes in space group P \(\overline 1\), with a = 8.8971(10) Å, b = 11.5440(13) Å, c = 11.9169(14) Å, α = 77.254(2)°, β = 74.079(2)°, and γ = 82.162(2)° compound 4 crystallizes in space group P21/c, with a = 10.3600(13) Å, b = 12.5650(16) Å, c = 9.9853(12) Å, and β = 103.599(2)°. Compound 1 crystallizes in a typical inorganic–organic layered structure adopted by metal naphthalenesulfonate, while compounds 2–4 crystallize in a hybrid inorganic–organic pattern. Unlike their Cu2+ analogue, the sulfonate does not coordinate directly to Ni2+. The hydrogen bonds formed between sulfonate and water molecules are the predominant packing forces for all structures. The inherited inversion center of the 1,5nds anion is carried into the crystal structure and results in centrosymmetric crystallization of all compounds.
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Chen, CH., Cai, J., Feng, XL. et al. Synthesis and crystal structures of four nickel(II) 1,5-naphthalenedisulfonate compounds. Journal of Chemical Crystallography 31, 271–280 (2001). https://doi.org/10.1023/A:1014326712278
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DOI: https://doi.org/10.1023/A:1014326712278